Photocatalytic mechanism of tourmaline/BiVO4 composites with different ratios

被引:5
|
作者
Qi, Shuyan [1 ]
Zhao, Yadong [1 ]
Ma, Ninglong [1 ]
Xu, Huanyan [1 ]
机构
[1] Harbin Univ Sci & Technol, Dept Mat Sci & Engn, Harbin 150040, Heilongjiang, Peoples R China
关键词
Tourmaline; methylene blue; photocatalytic; first-order kinetic; BIVO4; TIO2; DEGRADATION; STRATEGIES;
D O I
10.1080/24701556.2019.1661465
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The effect of the proportion tourmaline (0%, 1%, 3%, 5%, 7%, 9%) on the photocatalytic properties of BiVO4 was studied. The results were characterized by XRD, SEM, TEM, PL spectroscopy and UV-vis DRS. The first-order kinetic model was employed to fit the experiment. The results showed that the addition 3% tourmaline improved the degradation rate of methylene blue by BiVO4 from 47.7% to 82.1%. The addition of tourmaline can reduce the electrons and holes recombination rate of BiVO4 to a certain extent, and greatly reduced the forbidden band width. resulting in more conducive to the photocatalytic reaction, thereby improving its photocatalytic efficiency.
引用
收藏
页码:28 / 34
页数:7
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