Triterpenoid Saponins From the Stem Bark of Pentaclethra eetveldeana

被引:3
|
作者
Pertuit, David [1 ]
Kapundu, Mpuza [2 ]
Mitaine-Offer, Anne-Claire [1 ]
Miyamoto, Tomofumi [3 ]
Tanaka, Chiaki [3 ]
Delaude, Clement [4 ]
Lacaille-Dubois, Marie-Aleth [1 ]
机构
[1] Univ Bourgogne Franche Comte, UFR Sci Sante, PEPITE, Lab Pharmacognosie,EA 4267, 7,Bd Jeanne Arc,BP 87900, F-21079 Dijon, France
[2] Univ Kinshasa, Fac Sci Pharmaceut, Ctr Etud Subst Nat Origine Vegetale, Kinshasa, DEM REP CONGO
[3] Kyushu Univ, Grad Sch Pharmaceut Sci, Fukuoka, Fukuoka, Japan
[4] Univ Liege, Inst Chim, Ctr Rech Phytochim, B-6, Liege, Belgium
关键词
Pentaclethra eetveldeana; Fabaceae; triterpene saponins; 2D NMR; MS; GLYCOSIDES; ROOTS;
D O I
10.1177/1934578X19863947
中图分类号
R914 [药物化学];
学科分类号
100701 ;
摘要
Two previously undescribed triterpenoid saponins together with 4 known ones were isolated from the stem bark of Pentaclethra eetveldeana De Wild. & Th. Dur. Their structures were elucidated by spectroscopic methods including 1D and 2D NMR experiments in combination with mass spectrometry as 3-O-beta-D-glucopyranosyl-(1 -> 2)-[beta-D-glucopyranosyl-(1 -> 3)]-beta-D-glucopyranosyl-(1 -> 4)-beta-D-glucopyranosyl-(1 -> 3)-alpha-L-rhamnopyranosyl-(1 -> 2)-[beta-D-glucopyranosyl-(1 -> 4)]-alpha-L-arabinopyranosyloleanolic acid and 3-O-beta-D-glucopyranosyl-(1 -> 2)-[beta-D-glucopyranosyl-(1 -> 3)]-beta-D-glucopyranosyl-(1 -> 4)-beta-D-glucopyranosyl-(1 -> 3)-alpha-L-rhamnopyranosyl-(1 -> 2)-[beta-D-glucopyranosyl-(1 -> 4)]-alpha-L-arabinopyranosylhederagenin.
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页数:5
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