Effect of Ru nanoparticle size on hydrogenation of soybean oil

被引：10

作者：

Xu, Binbin ^{[1
]}

Liew, Kong Yong ^{[1
]}

Li, Jinlin ^{[1
]}

机构：

[1] S Cent Univ Nationalities, Coll Chem & Mat Sci, Key Lab Catalysis & Mat Sci Hubei Prov, Wuhan 430074, Peoples R China

来源：

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY | 2007年 / 84卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Ru; nanoparticles; hydrogenation; soybean oil; selectivity;

D O I：

10.1007/s11746-006-1014-4

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Four Ru nanoparticles of different mean sizes from 1.13 to 17.22 nm were prepared and used as catalysts for the selective hydrogenation of polyunsaturated soybean oil at 353 K and initial pressure of 1.5 MPa. The catalyst with the smallest mean size (1.13 nm) had the lowest activity, the activity increased as the mean size increased to 3.10 nm, then decreased with further increase in the mean particle size. The cis-trans isomerization rate decreased with the increase in particle size.

引用

页码：117 / 122

页数：6

共 50 条

[1] Effect of Ru nanoparticle size on hydrogenation of soybean oil
Xu, Binbin
Liew, Kong Yong
Li, Jinlin
[J]. JAOCS, Journal of the American Oil Chemists' Society, 2007, 84 (02): : 117 - 122
[2] EFFECT OF AGITATION ON SELECTIVITY IN THE HYDROGENATION OF SOYBEAN OIL
BEAL, RE
LANCASTER, EB
[J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1954, 31 (12) : 619 - 625
[3] Effect of hydrogenation on some chemical properties of soybean oil
Kayahan, Muammer
Tekin, Aziz
Kucuk, Mehmet
Karabacak, Hulya
Javidipour, Issa
[J]. Turk Tarim ve Ormancilik Dergisi/Turkish Journal of Agriculture and Forestry, 1999, 23 (Suppl. 3): : 541 - 547
[4] Hydrogenation of soybean oil triglycerides: Effect of pressure on selectivity
List, GR
Neff, WE
Holliday, RL
King, JW
Holser, R
[J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2000, 77 (03) : 311 - 314
[5] HYDROGENATION OF CLAY TREATED SOYBEAN OIL - EFFECT OF PHOSPHORUS
OKONEK, DV
SULLIVAN, TJ
NEBESH, O
[J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1986, 63 (04) : 450 - 451
[6] HOMOGENEOUS HYDROGENATION OF SOYBEAN OIL
GOLDSTEIN, S
RAVE, I
DOLEV, A
[J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1984, 61 (04) : 654 - 654
[7] THE ELECTROCATALYTIC HYDROGENATION OF SOYBEAN OIL
YUSEM, GJ
PINTAURO, PN
[J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1992, 69 (05) : 399 - 404
[8] ULTRASONIC HYDROGENATION OF SOYBEAN OIL
MORRIS, C
[J]. FOOD ENGINEERING, 1983, 55 (11): : 96 - 97
[9] ULTRASONIC HYDROGENATION OF SOYBEAN OIL
MOULTON, KJ
KORITALA, S
FRANKEL, EN
[J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1983, 60 (07) : 1257 - 1258
[10] Hydrogenation of oxidized soybean oil
[J]. Covey, Jesse E., 1600, (68):

← 1 2 3 4 5 →