Influence of the sol-gel method on a NiO/Al2O3 catalyst for CH4/O2 to syngas reaction

被引:8
|
作者
Zhang, YH
Xiong, GX
Kou, Y
Yang, WS
Sheng, SS
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
[2] Beijing Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
来源
关键词
nickel-based catalyst; methane partial oxidation to syngas; sol-gel; carbon-deposition;
D O I
10.1023/A:1005660102584
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
NiO/gamma-Al2O3 catalysts were prepared by the impregnation and the sol-gel method. The sintering and loss of nickel, carbon deposition and 80 h life-test for POM reaction over the catalyst were investigated by a now-reactor and by XPS, TG, EXAFS and AAS analysis. The results indicated that the sol-gel method could enhance the ability to suppress carbon deposition and to resist nickel sintering and loss over nickel-based catalysts.
引用
收藏
页码:325 / 329
页数:5
相关论文
共 50 条
  • [1] Influence of the Sol-Gel Method on a NiO/Al2O3 Catalyst for CH4/O2 to Syngas Reaction
    Yuhong Zhang
    Guoxing Xiong
    Yuan Kou
    Weishen Yang
    Shishan Sheng
    [J]. Reaction Kinetics and Catalysis Letters, 2000, 69 : 325 - 329
  • [2] The effect of Li and La on NiO/Al2O3 catalyst for CH4/O2 to syngas reaction
    Liu, SL
    Xiong, GX
    Yang, WS
    Sheng, SS
    [J]. REACTION KINETICS AND CATALYSIS LETTERS, 1999, 68 (02): : 243 - 247
  • [3] The effect of Li and La on NiO/Al2O3 catalyst for CH4/O2 to syngas reaction
    Shenglin Liu
    Guoxing Xiong
    Weishen Yang
    Shishan Sheng
    [J]. Reaction Kinetics and Catalysis Letters, 1999, 68 : 243 - 247
  • [5] The Effect of CaAl2O4 Spinel on Ni/Al2O3 Catalyst for CH4/O2-to-Syngas Reaction
    LU Yong LIU Yu SHEN Shikong (Lanzhou Institute of Chemical Physics The Chinese Academy of Sciences Lanzhou 730000)
    [J]. 分子催化, 1997, (03) : 6 - 7
  • [6] The mechanism of the CH4/O2 reaction on the Pd-Pt/γ-Al2O3 catalyst: A SSITKA study
    Rotko, Marek
    Machocki, Andrzej
    Slowik, Grzegorz
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 160 : 298 - 306
  • [7] KINETICS OF TRANSESTERIFICATION REACTION USING CAO/AL2O3 CATALYST SYNTHESIZED BY SOL-GEL METHOD
    Moradi, Gholamreza
    Davoodbeygi, Yegane
    Mohadesi, Majid
    Hosseini, Shokoufe
    [J]. CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 2015, 93 (05): : 819 - 824
  • [8] A plasma-activated Ni/α-Al2O3 catalyst for the conversion of CH4 to syngas
    Zhang, Y
    Chu, W
    Cao, WM
    Luo, CR
    Wen, XG
    Zhou, KL
    [J]. PLASMA CHEMISTRY AND PLASMA PROCESSING, 2000, 20 (01) : 137 - 144
  • [9] A Plasma-Activated Ni/α-Al2O3 Catalyst for the Conversion of CH4 to Syngas
    Yong Zhang
    Wei Chu
    Weimin Cao
    Chunrong Luo
    Xiaogang Wen
    Kunlin Zhou
    [J]. Plasma Chemistry and Plasma Processing, 2000, 20 : 137 - 144
  • [10] SYNTHESIS AND CHARACTERIZATION OF AL2O3 CATALYST CARRIERS BY SOL-GEL
    SIMON, C
    BREDESEN, R
    GRONDAL, H
    HUSTOFT, AG
    TANGSTAD, E
    [J]. JOURNAL OF MATERIALS SCIENCE, 1995, 30 (21) : 5554 - 5560