The metal-directed self-assembly of three-dimensional porphyrin arrays

被引:49
|
作者
Chichak, K [1 ]
Branda, NR [1 ]
机构
[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada
关键词
D O I
10.1039/b002562n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Six metalloporphyrins spontaneously assemble into octahedral arrays through a metal-directed synthesis; H-1 NMR provides a convenient means for tracking the progress of the self-assembly process and highlights that the rates in which the octahedral complexes form are influenced by the steric demands of the building blocks.
引用
收藏
页码:1211 / 1212
页数:2
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