Facile C-S Bond Cleavage of Aryl Sulfoxides Promoted by Bronsted Acid

被引：1
|
作者：
Brutiu, Bogdan R. [1 ]
Klose, Immo [1 ]
Maulide, Nuno [1 ]
机构：
[1] Univ Vienna, Inst Organ Chem, Wahringer Str 38, A-1090 Vienna, Austria
来源：
SYNLETT | 2021年 / 32卷 / 05期
基金：
欧盟地平线“2020”;
关键词：
sulfoxides; protodesulfination; deprotection; acid;
D O I：
10.1055/s-0040-1707109
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A method for the Bronsted acid promoted desulfination of aryl sulfoxides is presented. In the presence of a thiol, electron-rich sulfoxides undergo C-S bond cleavage to give the corresponding protodesulfinated arenes and disulfides.
引用
收藏
页码：488 / 490
页数：3
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