Transition-Metal-Free Aryl-Heteroatom Bond Formation via C-S Bond Cleavage

被引：53
|
作者：
Zhao, Jian-Nan [1 ,3 ]
Kayumov, Muzaffar [1 ,2 ]
Wang, Dong-Yu [1 ,2 ]
Zhang, Ao [1 ,2 ,3 ]
机构：
[1] SIMM, CAS Key Lab Receptor Res, Shanghai 201203, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] ShanghaiTech Univ, Sch Life Sci & Technol, Shanghai 201210, Peoples R China
来源：
ORGANIC LETTERS | 2019年 / 21卷 / 18期
基金：
中国博士后科学基金;
关键词：
CATALYZED SILYLATION; ARYLSULFONIUM SALTS; COUPLING REACTIONS; PALLADIUM; MILD; FUNCTIONALIZATION; STANNYLATION; CONSTRUCTION; CHEMISTRY; ARYLATION;
D O I：
10.1021/acs.orglett.9b02584
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Aryl-heteroatom bonds (C-Het) are almost ubiquitously present in chemical molecules. However, methods for diverse C-Het bond formations from a simple substrate are limited. Herein, we report a convenient and efficient C-S bond transformation of aryl sulfoniums to various C-Het bonds (C-O, C-S, C-Sn, C-Si, C-Se) in the absence of any transition-metal catalyst. These reactions proceeded in mild conditions with a wide substrate scope.
引用
收藏
页码：7303 / 7306
页数：4
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