An Enantiocomplementary Dirigent Protein for the Enantioselective Laccase-Catalyzed Oxidative Coupling of Phenols

被引：127

作者：

Pickel, Benjamin ^{[2
]}

Constantin, Mihaela-Anca ^{[1
]}

Pfannstiel, Jens ^{[3
,4
]}

Conrad, Juergen ^{[1
]}

Beifuss, Uwe ^{[1
]}

Schaller, Andreas ^{[2
]}

机构：

[1] Univ Hohenheim, Inst Chem, D-70599 Stuttgart, Germany

[2] Univ Hohenheim, Inst Physiol & Biotechnol Pflanzen, D-70599 Stuttgart, Germany

[3] Univ Hohenheim, Life Sci Ctr, D-70593 Stuttgart, Germany

[4] Univ Hohenheim, Inst Physiol, D-70593 Stuttgart, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 01期

关键词：

arabidopsis; dirigent proteins; enantioselectivity; lignans; phenol couplings; SHIRAIA-BAMBUSICOLA; BIOSYNTHESIS; EXPRESSION; VIOXANTHIN;

D O I：

10.1002/anie.200904622

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(+)- or (-)-plnoreslnol: that Is the question. Which of the two enantiomeric lignans is formed during laccasecatalyzed phenol coupling of (E)-coniferyl alcohol (1) depends on the dirigent protein. In the presence of the first enantiocomplementary dirigent protein AtDIR6, (-)-2 is formed (78 % ee). Preferential formation of (+)-2 is observed in the presence of the dirigent protein FiDIR1, whereas only racemic 2 is formed in the absence of dirigent proteins © 2010 Wiley-VCHVerlag GmbH & Co. KCaA, Weinheim.

引用

页码：202 / 204

页数：3

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