Laccase-catalyzed oxidative polymerization of phenols

被引：77
|
作者：
Mita, N
Tawaki, S
Uyama, H
Kobayashi, S
机构：
[1] Japan Chem Innovat Inst, Joint Res Ctr Precis Polymerizat, NIMC, Tsukuba, Ibaraki 3058565, Japan
[2] Mitsui Chem Inc, Catalysis Sci Lab, Chiba 2990265, Japan
[3] Kyoto Univ, Dept Chem Mat, Grad Sch Engn, Kyoto 6068501, Japan
来源：
MACROMOLECULAR BIOSCIENCE | 2003年 / 3卷 / 05期
关键词：
enzymes; laccase; oxidative polymerization; phenols; polyaromatics;
D O I：
10.1002/mabi.200390032
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Laccase-catalyzed oxidative polymerization of phenol and its derivatives has been performed in aqueous organic solvents at room temperature in air. Laccase derived from Pycnoporus coccineus efficiently induced the polymerization to produce polyphenols consisting of a mixture of phenylene and oxyphenylene units. The unit ratio of the polymer could be precisely controlled by selection of the solvent and the monomer substituent.
引用
收藏
页码：253 / 257
页数：5
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