Synthesis, Characterization and X-ray Crystal Structure of the Di-Mannich Base 2,2'-(3aR,7aR/3aS,7aS)-Hexahydro-1H-benzo[d]imidazole-1,3(2H)-diyl)bis(methylene)bis(4-methylphenol)

被引：10

作者：

Rivera, Augusto ^{[1
]}

Quiroga, Diego ^{[1
]}

Rios-Motta, Jaime ^{[1
]}

Carda, Juan ^{[2
]}

Peris, Gabriel ^{[3
]}

机构：

[1] Univ Nacl Colombia, Dept Quim, Bogota, Colombia

[2] Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, Spain

[3] Univ Jaume 1, Serv Cent Instrumentacio Cient, Castellon de La Plana 12071, Spain

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2009年 / 39卷 / 11期

关键词：

Di-Mannich bases; 2,2 '-(3aR,7aR/3aS,7aS)-Hexahydro-1H-benzo[d]imidazole-; 1,3(2H)-diyl)bis(methylene)bis(4-methylphenol); Crystal structure; Intramolecular hydrogen bond; Aminal cage; HYDROGEN-BONDS; DERIVATIVES; H-1-NMR; AMINALS; PRODUCT; COMPLEX; SCHIFF; SYSTEM; LIGAND; SALAN;

D O I：

10.1007/s10870-009-9578-0

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of new racemic di-Mannich base 2,2'-(3aR,7aR/3aS,7aS)-hexahydro-1H-benzo[d]imidazole-1,3(2H)-diyl)bis(methylene)bis(4-methylphenol) (4), is reported. The structure of the title compound, C(23)H(30)N(2)O(2), shows two intramolecular O-H center dot center dot center dot N hydrogen bonding interactions. This compound crystallizes in triclinic symmetry, in space group P-1, with lattice constants: a = 6.2563(3) angstrom, b = 12.1743(7) angstrom, c = 14.7257(7) angstrom, alpha = 108.11(1)degrees, beta = 99.77(1)degrees, gamma = 98.78(1), V = 1024.97(9) (3), Z = 2, F(000) = 396, R (1) = 8.3%, wR (2) = 14.7%.

引用

页码：827 / 830

页数：4

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