Dichloroacetonitrile hydrogenation by osmium cluster: Crystal structure of (μ-Cl)Os3(CO)10(μ-N=CHCHCl2)

被引：2

作者：

Savkov, Boris Yu. ^{[1
]}

Virovets, Alexander V. ^{[1
,2
]}

Maksakov, Vladimir A. ^{[1
,2
]}

机构：

[1] RAS, Nikolaev Inst Inorgan Chem SB, Ak Lavrentiev Str 3, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Pirogova Str 2, Novosibirsk 630090, Russia

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2017年 / 1141卷

关键词：

Osmium clusters; Hydrogenation; Transition metal cluster hydrides; MU-HYDRIDO-DECACARBONYLTRIOSMIUM; CARBONYL HYDRIDES; MOLECULAR-GEOMETRY; TRIOSMIUM CLUSTERS; H2OS3(CO)10; COMPLEXES; LIGANDS; NITRILE; IRON; ISOMERIZATION;

D O I：

10.1016/j.molstruc.2017.03.093

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dichloroacetonitrile undergoes hydrogenation by triosmium dihydride cluster under mild conditions. The reaction of cluster complex (mu-H)(2)Os-3(CO)(10) (1) with CHCl2CN in the presence of morpholine as a base results in two novel compounds (mu-Cl)Os-3(CO)(10)(mu-N=CHCHCl2) (2) and (mu-H)Os-3(CO)(10)(mu,eta(2)-HN=CHCHCl2) (3). Both compounds were characterized using FTIR, C-13, H-1 NMR spectra, and CHN analysis, molecular structure of 2 was determined by X-Ray diffraction study. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：115 / 118

页数：4

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