Thermally Activated Delayed Fluorescence from Sn4+-Porphyrin Complexes and Their Application to Organic Light-Emitting Diodes - A Novel Mechanism for Electroluminescence

被引：855
|
作者：
Endo, Ayataka [1 ]
Ogasawara, Mai [2 ]
Takahashi, Atsushi [3 ]
Yokoyama, Daisuke [1 ]
Kato, Yoshimine [2 ]
Adachi, Chihaya [1 ]
机构：
[1] Kyushu Univ, Ctr Future Chem, Nishi Ku, Fukuoka 8190395, Japan
[2] Kyushu Univ, Dept Mat Sci & Engn, Nishi Ku, Fukuoka 8190395, Japan
[3] Sogo Pharmaceut Co Ltd, Iwaki, Fukushima 9728312, Japan
来源：
ADVANCED MATERIALS | 2009年 / 21卷 / 47期
关键词：
DEVICES; ELECTROPHOSPHORESCENCE; PHOSPHORESCENCE;
D O I：
10.1002/adma.200900983
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Electroluminescence based on TADF, that is, thermally activated delayed fluorescence, is demonstrated in Sn4+-porphyrin complexes. On excitation by a short electrical pulse, prompt and delayed electroluminescence components were clearly observed. The delayed component was composed of both TADF and phosphorescence (see figure), and the TADF component significantly increased with increasing temperature.
引用
收藏
页码：4802 / +
页数：6
相关论文
共 50 条
  • [31] Thermally Activated Delayed Fluorescence Benzyl Cellulose Derivatives for Nondoped Organic Light-Emitting Diodes
    Shibano, Masaya
    Ochiai, Hiroki
    Suzuki, Katsuaki
    Kamitakahara, Hiroshi
    Kaji, Hironori
    Takano, Toshiyuki
    MACROMOLECULES, 2020, 53 (08) : 2864 - 2873
  • [32] Organoboron Complexes as Thermally Activated Delayed Fluorescence (TADF) Materials for Organic Light-Emitting Diodes (OLEDs): A Computational Study
    Asiri, Jamilah A.
    Hasan, Walid M. I.
    Jedidi, Abdesslem
    Elroby, Shaaban A.
    Aziz, Saadullah G.
    Osman, Osman I.
    MOLECULES, 2023, 28 (19):
  • [33] Efficient thermally activated delayed fluorescence of functional phenylpyridinato boron complexes and high performance organic light-emitting diodes
    Shiu, Yi-Jiun
    Chen, Yi-Ting
    Lee, Wei-Kai
    Wu, Chung-Chih
    Lin, Tzu-Chieh
    Liu, Shih-Hung
    Chou, Pi-Tai
    Lu, Chin-Wei
    Cheng, I-Chen
    Lien, Yi-Jyun
    Chi, Yun
    JOURNAL OF MATERIALS CHEMISTRY C, 2017, 5 (06) : 1452 - 1462
  • [34] Pyridyl Pyrrolide Boron Complexes: The Facile Generation of Thermally Activated Delayed Fluorescence and Preparation of Organic Light-Emitting Diodes
    Shiu, Yi-Jiun
    Cheng, Yung-Chen
    Tsai, Wei-Lung
    Wu, Chung-Chih
    Chao, Chun-Tien
    Lu, Chin-Wei
    Chi, Yun
    Chen, Yi-Ting
    Liu, Shih-Hung
    Chou, Pi-Tai
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (09) : 3017 - 3021
  • [35] Thermally activated delayed fluorescence emitters with dual conformations for white organic light-emitting diodes: mechanism and molecular design
    Li, Feiyan
    Jiang, Guanyu
    Li, Muzhen
    Fan, Jianzhong
    Song, Yuzhi
    Wang, Chuan-Kui
    Lin, Lili
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2020, 22 (03) : 1313 - 1323
  • [36] Photophysical studies of molecules with thermally activated delayed fluorescence for application in organic light emitting diodes
    Palmeira, Tiago
    Torres, Erica
    Alexandra Esteves, M.
    Brites, Maria Joao
    Berberan-Santos, Mario
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [37] The application of charge transfer host based exciplex and thermally activated delayed fluorescence materials in organic light-emitting diodes
    Wang, Ziqi
    Wang, Chao
    Zhang, Heng
    Liu, Zemei
    Zhao, Bo
    Li, Wenlian
    ORGANIC ELECTRONICS, 2019, 66 : 227 - 241
  • [38] Light blue and green thermally activated delayed fluorescence from 10H-phenoxaborin-derivatives and their application to organic light-emitting diodes
    Kitamoto, Yuichi
    Namikawa, Taketo
    Ikemizu, Dai
    Miyata, Yasuo
    Suzuki, Takatsugu
    Kita, Hiroshi
    Sato, Tetsuo
    Oi, Shuichi
    JOURNAL OF MATERIALS CHEMISTRY C, 2015, 3 (35) : 9122 - 9130
  • [39] Thermally activated delayed fluorescence exciplex emitters for high-performance organic light-emitting diodes
    Zhang, Ming
    Zheng, Cai-Jun
    Lin, Hui
    Tao, Si-Lu
    MATERIALS HORIZONS, 2021, 8 (02) : 401 - 425
  • [40] The effect of molecular aggregation of thermally activated delayed fluorescence sensitizers for hyperfluorescence in organic light-emitting diodes
    Park, Eun Young
    Park, Ji Hyun
    Kim, Yun-Hi
    Suh, Min Chul
    JOURNAL OF MATERIALS CHEMISTRY C, 2022, 10 (12) : 4705 - 4716
12345