Diol-Functionalized Imidazolium-Based Room-Temperature Ionic Liquids with Bis(trifluoromethanesulfonimide) Anions that Exhibit Variable Water Miscibility

被引：16
|
作者：
LaFrate, Andrew L. [1 ]
Bara, Jason E. [1 ,2 ]
Gin, Douglas L. [1 ,2 ]
Noble, Richard D. [1 ,2 ]
机构：
[1] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA
[2] Univ Colorado, Dept Chem & Biol Engn, Boulder, CO 80309 USA
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2009年 / 48卷 / 18期
关键词：
SELECTIVITY; EFFICIENT; EXTRACTION; SOLVENTS;
D O I：
10.1021/ie900460r
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The synthesis and characterization of a new class of 1-(2,3-dihydroxypropyl)-3-alkylimidazolium bis(trifluoromethanesulfonimide) room-temperature ionic liquids (RTIL.s) with tunable water miscibility are reported. The presence of a vicinal diol substituent oil these RTILs allows for variable water miscibility, depending on the nature of the alkyl substituent oil the cation. Water-miscible, imidazolium-based RTILs with the bis(trifluoromethanesulfonimide) anion are unprecedented.
引用
收藏
页码：8757 / 8759
页数：3
相关论文
共 50 条
  • [31] Faraday effect and refractive index of some imidazolium-based room- temperature ionic liquids and magnetic ionic liquids
    Koralewski, Marceli
    Paprzycka, Malgorzata
    JOURNAL OF MOLECULAR LIQUIDS, 2023, 375
  • [32] Stability of the Liquid State of Imidazolium-Based Ionic Liquids under High Pressure at Room Temperature
    Yoshimura, Yukihiro
    Shigemi, Machiko
    Takaku, Mayumi
    Yamamura, Misaho
    Takekiyo, Takahiro
    Abe, Hiroshi
    Hamaya, Nozomu
    Wakabayashi, Daisuke
    Nishida, Keisuke
    Funamori, Nobumasa
    Sato, Tomoko
    Kikegawa, Takurni
    JOURNAL OF PHYSICAL CHEMISTRY B, 2015, 119 (25): : 8146 - 8153
  • [33] A comparison of ether- and alkyl-derivatized imidazolium-based room-temperature ionic liquids: a molecular dynamics simulation study
    Smith, Grant D.
    Borodin, Oleg
    Li, Liyong
    Kim, Hojin
    Liu, Qin
    Bara, Jason E.
    Gin, Douglas L.
    Nobel, Richard
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (41) : 6301 - 6312
  • [34] Stability of Superoxide Ion in Imidazolium Cation-Based Room-Temperature Ionic Liquids
    Islam, Md. Mominul
    Imase, Tatsuya
    Okajima, Takeyoshi
    Takahashi, Mitsuo
    Niikura, Yoshihiro
    Kawashima, Norimichi
    Nakamura, Yoshiyuki
    Ohsaka, Takeo
    JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (05): : 912 - 916
  • [35] In Situ Attenuated Total Reflection Infrared Spectroscopy of Imidazolium-Based Room-Temperature Ionic Liquids under "Supercritical" CO2
    Seki, Tsunetake
    Grunwaldt, Jan-Dierk
    Baiker, Alfons
    JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (01): : 114 - 122
  • [36] Enhancing the CO2 Adsorption Performance of UiO-66 by Imidazolium-Based Room-Temperature Ionic Liquids (RTILs) Incorporation
    Mukaromah, Laela
    Haryanto, Andi
    Permana, Yessi
    Patah, Aep
    INDONESIAN JOURNAL OF CHEMISTRY, 2023, 23 (05) : 1406 - 1414
  • [37] Imidazolium-Based Ionic Liquids Catalyzed Formylation of Amines Using Carbon Dioxide and Phenylsilane at Room Temperature
    Hao, Leiduan
    Zhao, Yanfei
    Yu, Bo
    Yang, Zhenzhen
    Zhang, Hongye
    Han, Buxing
    Gao, Xiang
    Liu, Zhimin
    ACS CATALYSIS, 2015, 5 (09): : 4989 - 4993
  • [38] Enhanced refolding of lysozyme with imidazolium-based room temperature ionic liquids: Effect of hydrophobicity and sulfur residue
    Bae, Sang-Woo
    Chang, Woo-Jin
    Koo, Yoon-Mo
    Ha, Sung Ho
    SCIENCE CHINA-CHEMISTRY, 2012, 55 (08) : 1657 - 1662
  • [39] Enhanced refolding of lysozyme with imidazolium-based room temperature ionic liquids: Effect of hydrophobicity and sulfur residue
    BAE SangWoo
    CHANG WooJin
    KOO YoonMo
    HA Sung Ho
    Science China(Chemistry), 2012, 55 (08) : 1657 - 1662
  • [40] Europium(III) and its halides in anhydrous room-temperature imidazolium-based ionic liquids: A combined TRES, EXAFS, and molecular dynamics study
    Gaillard, C
    Billard, I
    Chaumont, A
    Mekki, S
    Ouadi, A
    Denecke, MA
    Moutiers, G
    Wipff, G
    INORGANIC CHEMISTRY, 2005, 44 (23) : 8355 - 8367
12345