Dielectric response of methyl isobutyl ketone (MIBK) in apolar solvents: solute-solvent interactions

被引：9

作者：

Dash, S. K. ^{[2
]}

Das, J. K. ^{[3
]}

Dalai, B. ^{[1
]}

Swain, B. B. ^{[1
]}

机构：

[1] Eastern Acad Sci & Technol, Dept Phys, Khurja 754001, Orissa, India

[2] Reg Inst Educ NCERT, DESM, Bhubaneswar 751022, Orissa, India

[3] Stewart Sci Coll, Dept Phys, Cuttack 753001, Orissa, India

来源：

INDIAN JOURNAL OF PHYSICS | 2009年 / 83卷 / 11期

关键词：

Dielectric constant; MIBK; binary mixture; SST; solute-solvent interaction; BINARY-MIXTURES; NONPOLAR-SOLVENTS; POLAR LIQUIDS; POLARIZATION; AMIDES;

D O I：

10.1007/s12648-009-0139-3

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Dielectric constants of binary mixtures of MIBK, an extractant used in nuclear energy industry, with six apolar solvents i.e. benzene, dioxane, cyclohexane, carbon tetrachloride, p-xylene and n-heptane have been measured at 455 kHz. The data are used to evaluate the Eyring's structural parameter, G*, in these systems to assess the nature of non-specific solute-solvent interaction. The value of G* is found to be influenced by the nature of the solvent.

引用

页码：1557 / 1566

页数：10

共 50 条

[31] SOLUTE-SOLVENT INTERACTIONS IN BIOINORGANIC CHEMISTRY
GRAY, HB
[J]. INORGANICA CHIMICA ACTA-ARTICLES, 1980, 40 (02): : X1 - X1
[32] Frictional effects in solute-solvent interactions
Canter, Neil
[J]. TRIBOLOGY & LUBRICATION TECHNOLOGY, 2009, 65 (01) : 12 - 13
[33] Highlights in solute-solvent interactions - Preface
Taube, H
[J]. MONATSHEFTE FUR CHEMIE, 2001, 132 (11): : 1235 - 1236
[34] Effects of solute-solvent and solvent-solvent attractive interactions on solute diffusion
Yamaguchi, T
Kimura, Y
[J]. MOLECULAR PHYSICS, 2000, 98 (19) : 1553 - 1563
[35] METHYL ISOBUTYL KETONE AS A SOLVENT FOR WAX DEOILING
LARIKOV, VI
ROSHCHIN, YN
SOKOLOVA, SP
PEREVERZEV, AN
[J]. CHEMISTRY AND TECHNOLOGY OF FUELS AND OILS, 1983, 19 (1-2) : 14 - 17
[36] DIELECTRIC STUDIES OF BINARY-MIXTURES OF SOME AMINES ANILINE AND PYRIDINE IN NONPOLAR-SOLVENTS SOLUTE-SOLVENT INTERACTIONS
TRIPATHY, S
SWAIN, BB
[J]. PHYSICS AND CHEMISTRY OF LIQUIDS, 1989, 20 (04) : 247 - 255
[37] PERCUTANEOUS UPTAKE AND KINETICS OF METHYL ISOBUTYL KETONE (MIBK) IN THE GUINEA-PIG
HJELM, EW
BOMAN, A
FERNSTROM, P
HAGBERG, M
JOHANSON, G
[J]. TOXICOLOGY LETTERS, 1991, 56 (1-2) : 79 - 86
[38] Biofiltration for removal of methyl isobutyl ketone (MIBK): Experimental studies and kinetic modelling
Raghuvanshi, Smita
Babu, B. V.
[J]. ENVIRONMENTAL TECHNOLOGY, 2010, 31 (01) : 29 - 40
[39] SOLUTE-SOLVENT INTERACTIONS IN SOLUTIONS OF POTASSIUM ACETATE IN WATER AND AQUEOUS METHYL ACETATE
BLOKHRA, RL
VERMA, PC
[J]. JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1980, 57 (10) : 991 - 994
[40] Solubility, thermodynamic properties and solute-solvent molecular interactions of luteolin in various pure solvents
Shakeel, Faiyaz
Haq, Nazrul
Alshehri, Sultan
Ibrahim, Mohamed A.
Elzayat, Ehab M.
Altamimi, Mohammad A.
Mohsin, Kazi
Alanazi, Fars K.
Alsarra, Ibrahim A.
[J]. JOURNAL OF MOLECULAR LIQUIDS, 2018, 255 : 43 - 50

← 1 2 3 4 5 →