Dielectric response of methyl isobutyl ketone (MIBK) in apolar solvents: solute-solvent interactions

被引：9

作者：

Dash, S. K. ^{[2
]}

Das, J. K. ^{[3
]}

Dalai, B. ^{[1
]}

Swain, B. B. ^{[1
]}

机构：

[1] Eastern Acad Sci & Technol, Dept Phys, Khurja 754001, Orissa, India

[2] Reg Inst Educ NCERT, DESM, Bhubaneswar 751022, Orissa, India

[3] Stewart Sci Coll, Dept Phys, Cuttack 753001, Orissa, India

来源：

INDIAN JOURNAL OF PHYSICS | 2009年 / 83卷 / 11期

关键词：

Dielectric constant; MIBK; binary mixture; SST; solute-solvent interaction; BINARY-MIXTURES; NONPOLAR-SOLVENTS; POLAR LIQUIDS; POLARIZATION; AMIDES;

D O I：

10.1007/s12648-009-0139-3

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Dielectric constants of binary mixtures of MIBK, an extractant used in nuclear energy industry, with six apolar solvents i.e. benzene, dioxane, cyclohexane, carbon tetrachloride, p-xylene and n-heptane have been measured at 455 kHz. The data are used to evaluate the Eyring's structural parameter, G*, in these systems to assess the nature of non-specific solute-solvent interaction. The value of G* is found to be influenced by the nature of the solvent.

引用

页码：1557 / 1566

页数：10

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