Development of hyperbranched polyester polyol-based waterborne anticorrosive coating

被引:22
|
作者
Singh, Ashish Pratap [1 ]
Suryanarayana, C. [1 ]
Naik, R. Baloji [1 ]
Gunasekaran, G. [1 ]
机构
[1] Naval Mat Res Lab, Shil Badlapur Rd,PO Anandnagar, Ambernath 421506, India
关键词
Waterborne; Hyperbranched polymers; Acid value; Anticorrosive coatings; RESINS; PAINT;
D O I
10.1007/s11998-015-9720-1
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Water-soluble hydroxyl functionalized hyperbranched polyester (WH-HP) resin was synthesized using pentaerythritol, pyromellitic dianhydride, phthalic anhydride, and 1,1,1-tris(hydroxymethyl) propane. The synthesized WH-HP was characterized by spectroscopic (FTIR and NMR) as well as thermal (TGA and DSC) analysis. WH-HP and hexa methoxy methyl melamine (HMMM) resins were mixed in different mole ratios (1: 2.5, 1: 5, 1: 7.5, and 1: 10), coated on mild steel panel, and cured by baking at 110 degrees C for 1 h. These coating compositions were evaluated for their mechanical and anticorrosive properties. It was observed that coating composition having 1: 5 mol ratio (WH-HP: HMMM) has shown very good mechanical and anticorrosive properties compared to the rest.
引用
收藏
页码:41 / 51
页数:11
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