Platinum(II) imidazo[4, 5-f]-1,10-phenanthroline chloride and thiolate complexes:: Synthesis and crystal structures

被引：26
|
作者：
Shavaleev, Nail M. [1 ]
Adams, Harry [1 ]
Weinstein, Julia A. [1 ]
机构：
[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England
来源：
INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 02期
基金：
英国工程与自然科学研究理事会;
关键词：
platinum; imidazo[4,5-f]-1,10-phenanthroline; thiolate; coordination compounds; X-ray crystal structures; charge-transfer; complex;
D O I：
10.1016/j.ica.2006.08.007
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The planar aromatic imidazo[4,5-f]-1,10-phenanthroline ligands have been used to prepare platinum(II) chloride and thiolate complexes. The X-ray structures of two thiolate compounds are reported, which show column-like packing in the solid state due to intermolecular aromatic pi-pi interactions. The compounds absorb moderately in the visible region, owing to {charge-transfer-to-diimine} electronic transition. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：700 / 704
页数：5
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