Islanding and critical phenomena it multi-component adsorption layer with lateral interactions

被引:1
|
作者
Murzin, DY [1 ]
机构
[1] LY KARPOV PHYS CHEM RES INST,DEPT CATALYSIS,MOSCOW 103064,RUSSIA
来源
REACTION KINETICS AND CATALYSIS LETTERS | 1996年 / 59卷 / 01期
关键词
lateral interactions; adsorbate segregation; adsorption isotherm; phase separation; critical temperature;
D O I
10.1007/BF02067999
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The conditions for the occurrence of critical phenomena in multi-component adsorption layers are discussed for the case of lateral interactions and clustering of adsorbed molecules. It is demonstrated, that the critical temperature. i.e. the temperature below which surface phase transformation can occur, is independent of the size of clusters.
引用
收藏
页码:111 / 116
页数:6
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