Gas Phase Hydrogenation of Levulinic Acid to γ-Valerolactone

被引：10

作者：

Bonrath, Werner ^{[1
]}

Castelijns, Anna Maria Cornelia Francisca ^{[2
]}

de Vries, Johannes Gerardus ^{[2
,3
]}

Guit, Rudolf Philippus Maria ^{[2
]}

Schuetz, Jan ^{[1
]}

Sereinig, Natascha ^{[2
]}

Vaessen, Henricus Wilhelmus Leonardus Marie ^{[2
]}

机构：

[1] DSM Nutrit Prod, Res & Dev Proc Res, POB 2676, CH-4002 Basel, Switzerland

[2] DSM ChemTech R&D, POB 18, NL-6160 MD Geleen, Netherlands

[3] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

CATALYSIS LETTERS | 2016年 / 146卷 / 01期

关键词：

Gas phase hydrogenation; Levulinic acid; gamma-Valerolactone; Copper catalyst; SELECTIVE HYDROGENATION; BIOMASS; CONVERSION; CATALYSTS; LIQUID;

D O I：

10.1007/s10562-015-1661-x

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The gas phase hydrogenation of levulinic acid to gamma-valerolactone over copper and ruthenium based catalysts in a continuous fixed-bed reactor system was investigated. Among the catalysts a copper oxide based one [50-75 % CuO, 20-25 % SiO2, 1-5 % graphite, 0.1-1 % CuCO3/Cu(OH)(2)] gave gamma-valerolactone in 93 % yield for more than 90 h constant operation. [GRAPHICS] .

引用

页码：28 / 34

页数：7

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