Hydrogenation of levulinic acid to γ-valerolactone using ruthenium nanoparticles

被引：73
|
作者：
Ortiz-Cervantes, Carmen [1 ]
Garcia, Juventino J. [1 ]
机构：
[1] Univ Nacl Autonoma Mexico, Fac Quim, Mexico City 04510, DF, Mexico
来源：
INORGANICA CHIMICA ACTA | 2013年 / 397卷
关键词：
Hydrogenation; Nanoparticles; Ruthenium; Levulinic acid; gamma-Valerolactone; Formic acid; CATALYTIC CONVERSION; FORMIC-ACID; STORAGE MATERIAL; BIOMASS; 1,4-PENTANEDIOL; GENERATION; LIQUID; METAL; FUELS;
D O I：
10.1016/j.ica.2012.11.031
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compound [Ru-3(CO)(12)] was used as precursor for the preparation of ruthenium nanoparticles of a typical size of <5 nm of diameter, without the use of additives. Such nanoparticles catalyzed the hydrogenation and cyclization of levulinic acid to selectively produce gamma-valerolactone in high yields, either using molecular hydrogen (H-2) or formic acid in water as reducing agents. (C) 2012 Elsevier B. V. All rights reserved.
引用
收藏
页码：124 / 128
页数：5
相关论文
共 50 条
  • [1] Water-Promoted Hydrogenation of Levulinic Acid to γ-Valerolactone on Supported Ruthenium Catalyst
    Tan, Jingjing
    Cui, Jinglei
    Deng, Tiansheng
    Cui, Xiaojing
    Ding, Guoqiang
    Zhu, Yulei
    Li, Yongwang
    [J]. CHEMCATCHEM, 2015, 7 (03) : 508 - 512
  • [2] KINETICS OF THE RUTHENIUM-CATALYZED HYDROGENATION OF LEVULINIC ACID TO γ-VALEROLACTONE IN AQUEOUS SOLUTIONS
    Jain, Anandkumar B.
    Vaidya, Prakash D.
    [J]. CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 2016, 94 (12): : 2364 - 2372
  • [3] Selective hydrogenation of levulinic acid to γ-valerolactone using in situ generated ruthenium nanoparticles derived from Ru-NHC complexes
    Tay, Boon Ying
    Wang, Cun
    Phua, Pim Huat
    Stubbs, Ludger Paul
    Huynh, Han Vinh
    [J]. DALTON TRANSACTIONS, 2016, 45 (08) : 3558 - 3563
  • [4] Interfacial acidity in ligand-modified ruthenium nanoparticles boosts the hydrogenation of levulinic acid to gamma-valerolactone
    Albani, Davide
    Li, Qiang
    Vile, Gianvito
    Mitchell, Sharon
    Almora-Barrios, Neyvis
    Witte, Peter T.
    Lopez, Nuria
    Perez-Ramirez, Javier
    [J]. GREEN CHEMISTRY, 2017, 19 (10) : 2361 - 2370
  • [5] Gas Phase Hydrogenation of Levulinic Acid to γ-Valerolactone
    Werner Bonrath
    Anna Maria Cornelia Francisca Castelijns
    Johannes Gerardus de Vries
    Rudolf Philippus Maria Guit
    Jan Schütz
    Natascha Sereinig
    Henricus Wilhelmus Leonardus Marie Vaessen
    [J]. Catalysis Letters, 2016, 146 : 28 - 34
  • [6] Alkali promotion of alumina-supported ruthenium catalysts for hydrogenation of levulinic acid to γ-valerolactone
    Cao, Shuo
    Monnier, John R.
    Regalbuto, John R.
    [J]. JOURNAL OF CATALYSIS, 2017, 347 : 72 - 78
  • [7] Ruthenium and Iridium Dipyridylamine Catalysts for the Efficient Synthesis of γ-Valerolactone by Transfer Hydrogenation of Levulinic Acid
    Wang, Shengdong
    Dorcet, Vincent
    Roisnel, Thierry
    Bruneau, Christian
    Fischmeister, Cedric
    [J]. ORGANOMETALLICS, 2017, 36 (03) : 708 - 713
  • [8] Gas Phase Hydrogenation of Levulinic Acid to γ-Valerolactone
    Bonrath, Werner
    Castelijns, Anna Maria Cornelia Francisca
    de Vries, Johannes Gerardus
    Guit, Rudolf Philippus Maria
    Schuetz, Jan
    Sereinig, Natascha
    Vaessen, Henricus Wilhelmus Leonardus Marie
    [J]. CATALYSIS LETTERS, 2016, 146 (01) : 28 - 34
  • [9] Efficient aqueous hydrogenation of levulinic acid to γ-valerolactone over a highly active and stable ruthenium catalyst
    Tan, Jingjing
    Cui, Jinglei
    Ding, Guoqiang
    Deng, Tiansheng
    Zhu, Yulei
    Li, Yong-wang
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (05) : 1469 - 1475
  • [10] A Comparative Study of Structurally Related Homogeneous Ruthenium and Iron Catalysts for the Hydrogenation of Levulinic Acid to -Valerolactone
    van Slagmaat, Christian A. M. R.
    De Wildeman, Stefaan M. A.
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018, (06) : 694 - 702
12345