Solvent- and Vapor-Mediated Solid-State Transformations in 1,3,5-Benzenetricarboxylate Metal-Organic Frameworks

被引：29
|
作者：
Davies, Kate [1 ]
Bourne, Susan A. [1 ]
Oliver, Clive L. [1 ]
机构：
[1] Univ Cape Town, Dept Chem, Ctr Supramol Chem Res, ZA-7701 Rondebosch, South Africa
来源：
CRYSTAL GROWTH & DESIGN | 2012年 / 12卷 / 04期
基金：
新加坡国家研究基金会;
关键词：
SECONDARY BUILDING UNITS; MN2+ COORDINATION SITES; CRYSTAL TRANSFORMATION; HYDROGEN STORAGE; H-2; ADSORPTION; POLYMERS; NETWORK; SEPARATION; MOFS; COMPLEXES;
D O I：
10.1021/cg201707e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of 1,3,5-benzenetricarboxylic acid (H3BTRI) with ZnSO4 center dot 7H(2)O in DMF and H2O afforded [Zn-2(mu(2)-OH2)(HBTRI)(BTRI)(H2O)(2)]center dot DMA center dot 3H(2)O (1). Compound 1 displays self-healing properties upon dehydration and rehydration as revealed by scanning electron microscopy. Further studies showed that 1 is flexible and able to absorb additional water molecules in high vapor pressure environments. The reaction of H3BTRI with Gd(NO3)(3)center dot 6H(2)O in DMF and H2O resulted in [Gd(BTRI)(H2O)(6)] (2). It is also possible to form compound 2 through a solid-state process when crystals of 1 are placed into a solution of Gd(NO3)(3)center dot 6H(2)O in DMF and H2O. The reverse process does not occur.
引用
收藏
页码：1999 / 2003
页数：5
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