Syntheses, Structures, and Structural Transformations of Mixed Na(I) and Zn(II) Metal-Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands

被引：21
|
作者：
Fu, Ying [1 ]
Su, Jie [1 ]
Yang, Sihai [2 ]
Zou, Zhibo [3 ]
Li, Guobao [1 ]
Liao, Fuhui [1 ]
Xiong, Ming [4 ]
Lin, Jianhua [1 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, BNLMS, Beijing 100871, Peoples R China
[2] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
[3] Beijing Huiwen Middle Sch, Beijing 100061, Peoples R China
[4] China Univ Geosci, Xray Lab, Beijing 100083, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2011年 / 11卷 / 06期
基金：
中国国家自然科学基金;
关键词：
POROUS COORDINATION-POLYMER; SINGLE-CRYSTAL TRANSFORMATIONS; SPIN-CROSSOVER; HYDROGEN-BOND; SORPTION; BEHAVIOR; CONSTRUCTION; COMPLEXES; MOLECULES; CHEMISTRY;
D O I：
10.1021/cg101610k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three new compounds, [ZnNa(BTC)(H2O)(2)]center dot H2O (1), [Zn3Na2(BTC)(2)(HCOO)(2)(H2O)(8)] (2), and [Zn3Na(BTC)(2) (HCOO)(H2O)3]center dot H2O (3) (H3BTC = 1,3,5-benzenetricarboxylate acid), were synthesized under hydrothermal conditions and were characterized by the single crystal and powder X-ray diffraction, IR spectra, elemental analyses, ICP measurements, and coupled TG-MS analyses. 1, 2, and 3 crystallize in the space groups P (1) over bar, C2/c, and P1, respectively. They are three-dimensional (3D) frameworks, consisting of zigzag chains ((Na2Zn2O14)(n) for 1, (Na2Zn3O18)(n) for 2, or (NaZn3O14)(n) for 3) and bridging BTC ligands. Powder X-ray diffraction studies reveal that 1 and 2 exhibit reversible dehydration-rehydration behaviors with a crystal-to-crystal transformation observed for 2.
引用
收藏
页码：2243 / 2249
页数：7
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