Synthesis of Propylene Carbonate by Urea Alcoholysis-Recent Advances

被引：10

作者：

Kotyrba, Lukasz ^{[1
,2
]}

Chrobok, Anna ^{[3
]}

Siewniak, Agnieszka ^{[3
]}

机构：

[1] Lukasiewicz Res Network, Inst Heavy Organ Synth Blachownia, Energetykow 9, PL-47225 Kedzierzyn Kozle, Poland

[2] Silesian Tech Univ, PhD Sch, Dept Chem Organ Technol & Petrochem, Akad 2A, PL-44100 Gliwice, Poland

[3] Silesian Tech Univ, Fac Chem, Dept Chem Organ Technol & Petrochem, Krzywoustego 4, PL-44100 Gliwice, Poland

来源：

CATALYSTS | 2022年 / 12卷 / 03期

关键词：

propylene carbonate; urea alcoholysis; propylene glycol; ZN-AL OXIDE; ONE-POT SYNTHESIS; 1,2-PROPYLENE GLYCOL; CATALYTIC PERFORMANCE; DIMETHYL CARBONATE; CYCLIC CARBONATES; EFFICIENT CATALYST; ETHYLENE CARBONATE; MIXED-OXIDE; TRANSESTERIFICATION;

D O I：

10.3390/catal12030309

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Organic carbonates are considered the chemicals of the future. In particular, propylene carbonate is widely used as a non-reactive solvent, plasticizer, fuel additive, and reagent, especially in the production of environmentally friendly polymers that are not harmful to human health. This paper reviews recent literature findings regarding the development of propylene carbonate synthetic methods starting from propane-1,2-diol and urea. The ammonia formed during the synthesis is recycled to obtain urea from carbon dioxide.

引用

页数：18

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