Self-assembly of one-dimensional polymers by coordination and hydrogen bonding in palladium(II) complexes

被引:35
|
作者
Qin, ZQ
Jenkins, HA
Coles, SJ
Muir, KW [1 ]
Puddephatt, RJ
机构
[1] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland
[2] CLRC Daresbury Lab, Warrington WA4 4AD, Cheshire, England
[3] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
关键词
polymer; hydrogen-bonding; palladium; coordination;
D O I
10.1139/cjc-77-1-155
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The ligands L = pyridine- or quinoline-carboxylic acid easily give complexes trans-[PdCl2L2], which self-assemble through hydrogen bonding between carboxylic acid groups to give one-dimensional polymers, as proved by structure determinations when L = NC5H4COOH-4, NC5H4COOH-3, and 2-Ph-NC9H5COOH-4.
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页码:155 / 157
页数:3
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