Single-crystal to single-crystal transformation of cyclic water heptamer to another (H2O)7 cluster containing cyclic pentamer

被引：57
|
作者：
Mir, Mohammad Hedayetullah [1 ]
Vittal, Jagadese J. [1 ]
机构：
[1] Natl Univ Singapore, Dept Chem, Fac Sci, Singapore 117543, Singapore
来源：
CRYSTAL GROWTH & DESIGN | 2008年 / 8卷 / 05期
关键词：
D O I：
10.1021/cg800244g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A discrete cyclic water heptamer trapped inside a three-dimensional coordination polymer undergoes single-crystal to singlecrystal transformation to a new type of water heptamer containing a pentamer ring buttressed by a dimer, accompanied by phase transition below 273 K. The structural differences between the heptamers in BF4- and ClO4- salts have been attributed to the influence of the anions in the channels.
引用
收藏
页码：1478 / 1480
页数：3
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