Gas-phase reaction of free diethylsilylium ions with hexamethyldisiloxane

被引：3
|
作者：
Kochina, TA [1 ]
Vrazhnov, DV
Sinotova, EN
Ignat'ev, IS
机构：
[1] Russian Acad Sci, IV Grebenshchikov Silicate Chem Inst, St Petersburg 196140, Russia
[2] St Petersburg State Univ, St Petersburg, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2005年 / 75卷 / 05期
关键词：
D O I：
10.1007/s11176-005-0303-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The gas-phase reaction of diethylsilylium ions with hexamethyldisiloxane was studied by the radiochemical procedure. As in reactions with other nucleophiles, the degree of rearrangement of the diethylsilylium ion in the reaction with hexamethyldisiloxane correlates with the condensation energy. In contrast to the reaction of Et2SiT+ with dibutyl ether, in the reaction with hexamethyldisiloxane the labeled substrate is formed, which is due to isomerization of the trimethylsilyl substituent giving rise to a labile hydrogen atom.
引用
收藏
页码：708 / 710
页数：3
相关论文
共 50 条
  • [1] Gas-Phase Reaction of Free Diethylsilylium Ions with Hexamethyldisiloxane
    T. A. Kochina
    D. V. Vrazhnov
    E. N. Sinotova
    I. S. Ignat’ev
    Russian Journal of General Chemistry, 2005, 75 : 708 - 710
  • [2] GAS-PHASE REACTION OF FREE ISOPROPYL IONS WITH PHENOL AND ANISOLE
    ATTINA, M
    CACACE, F
    CIRANNI, G
    GIACOMELLO, P
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1979, (07): : 891 - 895
  • [3] Radiochemical study of the gas phase reaction of nucleogenic diethylsilylium ions with methanol and butanol
    Kochina, TA
    Vrazhnov, DV
    Ignatyev, IS
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 656 (1-2) : 258 - 261
  • [4] THE GAS-PHASE REACTION OF FREE PHENYLIUM IONS WITH 1,3-BUTADIENE
    FORNARINI, S
    SPERANZA, M
    GAZZETTA CHIMICA ITALIANA, 1986, 116 (06): : 341 - 342
  • [5] Radiochemical study of the reactions of diethylsilylium ions with hexamethyldisilazane and isobutylamine in the gas phase
    Vrazhnov, DV
    Kochina, TA
    Sinotova, EN
    Ignat'ev, IS
    Kalinin, EO
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2005, 75 (09) : 1399 - 1401
  • [6] Ion-Molecular Reactions of Diethylsilylium Ions with Alcohols in the Gas Phase
    T. A. Kochina
    D. V. Vrazhnov
    I. S. Ignat'ev
    E. N. Sinotova
    Russian Journal of General Chemistry, 2003, 73 : 61 - 65
  • [7] Ion-molecular reactions of diethylsilylium ions with alcohols in the gas phase
    Kochina, TA
    Vrazhnov, DV
    Ignat'ev, IS
    Sinotova, EN
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2003, 73 (01) : 61 - 65
  • [8] Radiochemical Study of the Reactions of Diethylsilylium Ions with Hexamethyldisilazane and Isobutylamine in the Gas Phase
    D. V. Vrazhnov
    T. A. Kochina
    E. N. Sinotova
    I. S. Ignat'ev
    E. O. Kalinin
    Russian Journal of General Chemistry, 2005, 75 : 1399 - 1401
  • [9] DYNAMICS AND REACTION-MECHANISMS OF ORGANIC IONS IN THE GAS-PHASE
    BARFKNECHT, AT
    DODD, JA
    SALOMON, KE
    TUMAS, W
    BRAUMAN, JI
    PURE AND APPLIED CHEMISTRY, 1984, 56 (12) : 1809 - 1818
  • [10] HYDROXYLATION OF SELECTED HYDROCARBON IONS ON REACTION WITH METHANOL IN THE GAS-PHASE
    DOLNIKOWSKI, GG
    ALLISON, J
    WATSON, JT
    ORGANIC MASS SPECTROMETRY, 1990, 25 (02): : 119 - 123
12345