Modular Redox-Active Inorganic Chemical Cells: iCHELLs

被引：40
|
作者：
Cooper, Geoffrey J. T. [1 ]
Kitson, Philip J. [1 ]
Winter, Ross [1 ]
Zagnoni, Michele [2 ]
Long, De-Liang [1 ]
Cronin, Leroy [1 ]
机构：
[1] Univ Glasgow, Dept Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland
[2] Univ Strathclyde, Dept Elect & Elect Engn, Ctr Microsyst & Photon, Glasgow G1 1XW, Lanark, Scotland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 44期
基金：
英国工程与自然科学研究理事会;
关键词：
capsules; chemical cells; membranes; polyoxometalates; self-assembly; POLYMER CAPSULES; SELF; EQUILIBRIUM; MEMBRANES; SIZE; FILM;
D O I：
10.1002/anie.201105068
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cell within a cell: Interfacial membrane formation by cation exchange of polyoxometalates produces modular inorganic chemical cells with tunable morphology, properties, and composition (see picture). These inorganic chemical cells (iCHELLs), which show redox activity, chirality, as well as selective permeability towards small molecules, can be nested within one another, potentially allowing stepwise reactions to occur in sequence within the cell. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：10373 / 10376
页数：4
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