Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)center dot 0.3H(2)O}(n)], [Zn(oda)(bipy)(H2O)]center dot 2.5H(2)O and [Zn(oda)(phen)(H2O)]center dot 1.5H(2)O (bipy=2,2'-bipyridine, phen=1,10-phenanthroline)

被引：38

作者：

Baggio, R

Garland, MT

Perec, M

机构：

[1] UNIV BUENOS AIRES,INST QUIM FIS MAT MEDIO AMBIENTE & ENERGIA,DEPT QUIM INORGAN ANALIT & QUIM FIS,RA-1428 BUENOS AIRES,DF,ARGENTINA

[2] COMIS NACL ENERGIA ATOM,DEPT FIS,DIV FIS SOLIDO,RA-1429 BUENOS AIRES,DF,ARGENTINA

[3] UNIV CHILE,FAC CIENCIAS FIS & MATEMAT,DEPT FIS,SANTIAGO,CHILE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 13期

关键词：

D O I：

10.1039/dt9960002747

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three novel zinc(II) oxydiacetate (oda) compounds [{Zn(oda). 0.3H(2)O}(n)] 1, [Zn(oda)(bipy)(H2O)]. 2.5H(2)O 2 (bipy = 2,2'-bipyridine) and [Zn(oda)(phen)(H2O)]. 1.5H(2)O 3 (phen = 1,10-phenanthroline) have been synthesized and their structures determined by single-crystal X-ray diffraction methods. Compound 1 consists of polymeric sheets formed by ZnO5 units bridged by carboxylate groups in anti-syn conformation along the z axis; 2 and 3 are mononuclear with the zinc atoms in distorted octahedral ZnN2O4 co-ordination geometries. Thermal decomposition of the compounds under an oxygen atmosphere affords ZnO at ca. 500 degrees C.

引用

页码：2747 / 2753

页数：7

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