Efficient carbon-based solid acid catalysts for the esterification of oleic acid

被引：117
|
作者：
Geng, Liang [1 ]
Wang, Yu [1 ]
Yu, Gang [1 ]
Zhu, Yuexiang [1 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 10087, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2011年 / 13卷 / 01期
基金：
美国国家科学基金会;
关键词：
Carbon-based solid acid; Dispersion; Esterification; Biodiesel; ORDERED MESOPOROUS CARBON; ALUMINA; BIODIESEL;
D O I：
10.1016/j.catcom.2011.06.014
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A series of carbon-based solid acid catalysts was prepared by the sulfonation of mesoporous carbon substrates with thin pore walls, and catalytic activity for the esterification of oleic acid with methanol was tested. The highest turnover frequency (TOF) observed was 78 h(-1), five times that of Amberlyst-15. The high catalytic activity may be attributed to the good dispersion of the catalysts in methanol. Catalysts with improved dispersion were obtained by a modified preparation, after which the highest TOE observed was 109 h(-1), seven times that of Amberlyst-15. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：26 / 30
页数：5
相关论文
共 50 条
  • [21] Phosphotungstic acid and propylsulfonic acid bifunctionalized ordered mesoporous silica: A highly efficient and reusable catalysts for esterification of oleic acid
    Yu, Zhengfei
    Chen, Xifeng
    Zhang, Yibo
    Tu, Hongyu
    Pan, Pen
    Li, Shuai
    Han, Yuxiang
    Piao, Minjun
    Hu, Jianglei
    Shi, Fengwei
    Yang, Xia
    [J]. CHEMICAL ENGINEERING JOURNAL, 2022, 430
  • [22] Increased flexibility to improve the catalytic performance of carbon-based solid acid catalysts
    Hu, Shuanglan
    Huang, Junsheng
    Huang, Dongting
    Li, Peng
    Tang, Jingjie
    Meng, Fei
    [J]. GREEN PROCESSING AND SYNTHESIS, 2021, 10 (01) : 687 - 699
  • [23] Preparation of Magnetic Sulfonated Carbon-Based Solid Acid Catalysts for the Hydrolysis of Cellulose
    Wang Hua-Yu
    Zhang Chang-Bin
    He Hong
    Wang Lian
    [J]. ACTA PHYSICO-CHIMICA SINICA, 2010, 26 (07) : 1873 - 1878
  • [24] Efficient carbon-based acid catalysts for the propan-2-ol dehydration
    Diyuk, Vitaliy E.
    Zaderko, Alexander N.
    Grishchenko, Liudmyla M.
    Yatsymyrskiy, Andrii V.
    Lisnyak, Vladyslav V.
    [J]. CATALYSIS COMMUNICATIONS, 2012, 27 : 33 - 37
  • [25] Esterification by solid acid catalysts - a comparison
    Shanmugam, S
    Viswanathan, B
    Varadarajan, TK
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 223 (1-2) : 143 - 147
  • [26] SO3H-modified petroleum coke derived porous carbon as an efficient solid acid catalyst for esterification of oleic acid
    Wu, Mingbo
    Wang, Yang
    Wang, Ding
    Tan, Minghui
    Li, Peng
    Wu, Wenting
    Tsubaki, Noritatsu
    [J]. JOURNAL OF POROUS MATERIALS, 2016, 23 (01) : 263 - 271
  • [27] SO3H-modified petroleum coke derived porous carbon as an efficient solid acid catalyst for esterification of oleic acid
    Mingbo Wu
    Yang Wang
    Ding Wang
    Minghui Tan
    Peng Li
    Wenting Wu
    Noritatsu Tsubaki
    [J]. Journal of Porous Materials, 2016, 23 : 263 - 271
  • [28] Carbon-based solid acid catalyst derived from Undaria pinnatifida and its application in esterification
    Balasubramaniam, Shamala
    Ninomiya, Shohei
    Sasaki, Mitsuru
    Quitain, Armando
    Kida, Tetsuya
    Saldana, Marleny D. A.
    [J]. ALGAL RESEARCH-BIOMASS BIOFUELS AND BIOPRODUCTS, 2021, 55
  • [29] Preparation of carbon-based solid acid with large surface area to catalyze esterification for biodiesel production
    Tang Xincheng
    Niu Shengli
    [J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2019, 69 : 187 - 195
  • [30] Synthesis porous carbon-based solid acid from rice husk for esterification of fatty acids
    Zeng, Danlin
    Zhang, Qi
    Chen, Shiyuan
    Liu, Shenglan
    Wang, Guanghui
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2016, 219 : 54 - 58
12345