An electrochromic and fluorescent polymer based on 1-(1-naphthyl)-2,5-di-2-thienyl-1H-pyrrole

被引：63

作者：

Cihaner, Atilla ^{[1
]}

Algi, Fatih ^{[2
]}

机构：

[1] Atilim Univ, Chem Grp, Fac Engn, TR-06836 Ankara, Turkey

[2] Canakkale Onsekiz Mart Univ, Dept Chem, TR-17100 Canakkale, Turkey

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2008年 / 614卷 / 1-2期

关键词：

electrochemical polymerization; polythiophene; polypyrrole; naphthalene;

D O I：

10.1016/j.jelechem.2007.11.024

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A novel polymer was synthesized by electrochemical polymerization of 1-(1-naphthyl)-2,5-di-2-thienyl-1H-pyrrole (SNS-1-NAPH). The corresponding polymer (PSNS-1-NAPH) was characterized by cyclic voltammetry, FT-IR and UV-vis spectroscopy. The polymer has a very well-defined and reversible redox process in both organic and aqueous solutions. Furthermore, it shows stable electrochromic behavior; yellow in the neutral state, green in the intermediate state and violet in the oxidized state. PSNS-1-NAPH is soluble in common solvents. Although SNS-1-NAPH is almost nonfluorescent, its polymer is a yellow and/or green light emitter. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：101 / 106

页数：6

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