Platinum(II)-catalyzed Acetal-Ene Reaction: Easy Access to Homoallylic Ethers

被引：6
|
作者：
Miura, Katsukiyo [1 ]
Izumi, Hiroyuki [2 ]
Kinoshita, Hidenori [1 ]
Ichikawa, Junji [2 ]
Hosomi, Akira [2 ]
机构：
[1] Saitama Univ, Dept Appl Chem, Grad Sch Sci & Engn, Sakura Ku, Saitama 3388570, Japan
[2] Univ Tsukuba, Grad Sch Pure & Appl Sci, Dept Chem, Tsukuba, Ibaraki 3058571, Japan
来源：
CHEMISTRY LETTERS | 2009年 / 38卷 / 12期
关键词：
LEWIS; CYCLIZATIONS; MECHANISM; OLEFINS;
D O I：
10.1246/cl.2009.1204
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Catalytic use of PtCl2 and AgX (X = OTf and SbF6) has been found to effectively promote the intermolecular ene reaction of acetals and the tandem acetalization-ene reaction of aldehydes under solvent-free conditions.
引用
收藏
页码：1204 / 1205
页数：2
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