Copper Tetrasulfophthalocyanine Intercalated Hydrotalcite as an Efficient Bifunctional Catalyst for the Baeyer-Villiger Oxidation

被引：17

作者：

Zhou, Weiyou ^{[1
]}

Chen, Yong ^{[1
]}

Qian, Junfeng ^{[1
]}

Sun, Fu'an ^{[1
]}

He, Mingyang ^{[1
]}

Chen, Qun ^{[1
]}

机构：

[1] Changzhou Univ, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China

来源：

CATALYSIS LETTERS | 2016年 / 146卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Hydrotalcite-like compounds; Copper phthalocyanine; Baeyer-Villiger oxidation; Bifunctional catalyst; LAYERED DOUBLE HYDROXIDES; C-H BONDS; MOLECULAR-OXYGEN; CYCLIC-KETONES; HYDROGEN-PEROXIDE; AL-HYDROTALCITES; BENZALDEHYDE; CYCLOHEXANONE; PHTHALOCYANINE; SILICA;

D O I：

10.1007/s10562-016-1823-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A heterogeneous bifunctional hybrid catalyst originated from copper tetrasulfophthalocyanine (CuPcTs) and hydrotalcite for Baeyer-Villiger (B-V) oxidation has been prepared and characterized. XRD, FTIR, DR UV-Vis and SEM characterization indicate that CuPcTs molecule has been successfully intercalated into the layer of ZnAl hydrotalcite. And the synthesized hybrid exhibited excellent catalytic activity in the B-V oxidation for various ketones under mild conditions. Its bifunctional role in the reaction through O-2/benzaldehyde has been discussed and verified by controlled experiments. The study indicates that the designed catalyst not only catalyzes the oxidation of benzaldehyde to perbenzoic acid, but also accelerates the transformation of ketone to lactone or ester. [GRAPHICS] .

引用

页码：2157 / 2164

页数：8

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