Modification of Compounds Based on Ethylene-Propylene-Diene Rubbers Using an Oligomeric Unsaturated Polyketone

被引:2
|
作者
Voronchikhin, V. D. [1 ]
Dubkov, K. A. [2 ]
Sorochenko, O. V. [1 ]
Ivanov, D. P. [2 ]
Semikolenov, S. V. [2 ]
机构
[1] Reshetnev Siberian State Univ Sci & Technol, Krasnoyarsk 660037, Russia
[2] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia
基金
俄罗斯基础研究基金会;
关键词
vulcanization; polyketone; modification; ethylene-propylene-diene rubber; elastomers; NITROUS-OXIDE; KETONIZATION;
D O I
10.1134/S1070427220020068
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The efficiency of using an oligomeric unsaturated polyketone prepared by ketonization of cis-1,4-butadiene rubber with nitrogen(I) oxide (N2O) for the modification of physicomechanical properties of elastomer compounds based on Keltan 512 and SKEPT-50 ethylene-propylene-diene rubbers was demonstrated. The modification leads to a decrease in the viscosity of filled rubber stocks, facilitating their processing on the process equipment, and to more uniform dispersion of the silica filler (BS-1290 white soot); it enhances the elastic and strength characteristics of the vulcanizates by a factor of up to 2-2.5 relative to the unmodified compounds.
引用
收藏
页码:197 / 203
页数:7
相关论文
共 50 条
  • [21] Polypropylene crystallization in an ethylene-propylene-diene rubber matrix
    López Manchado M.A.
    Biagiotti J.
    Torre L.
    Kenny J.M.
    Journal of Thermal Analysis and Calorimetry, 2000, 61 (2) : 437 - 450
  • [22] Influence of diene content on the photodegradation of ethylene-propylene-diene (EPDM) Elastomers
    Botelho, G.
    Queiros, A.
    Silva, M. A.
    Conceicao, J.
    ADVANCED MATERIALS FORUM III, PTS 1 AND 2, 2006, 514-516 : 877 - 881
  • [23] Terahertz Spectroscopic Analysis of Ethylene-Propylene-Diene Copolymer
    Komatsu, Marina
    Izutsu, Tomoyuki
    Ohki, Yoshimichi
    Mizuno, Maya
    FUkunaga, Kaori
    Nakamura, Oshiaki
    Chiwata, Naofumi
    PROCEEDINGS OF 2014 INTERNATIONAL SYMPOSIUM ON ELECTRICAL INSULATING MATERIALS (ISEIM 2014), 2014, : 338 - 341
  • [24] Unusual behaviour of polyethylene in ethylene-propylene-diene matrix
    Bielinski, DM
    Slusarski, L
    Wlochowicz, A
    Douillard, A
    COMPOSITE INTERFACES, 1998, 5 (02) : 155 - 178
  • [25] Assessment of compatibility of ethylene-propylene-diene terpolymer and polypropylene
    Zaharescu, T
    POLYMER DEGRADATION AND STABILITY, 2001, 73 (01) : 113 - 118
  • [26] Miscibility of blends of ethylene-propylene-diene terpolymer and polypropylene
    Xiao, HW
    Huang, SQ
    Jiang, T
    Cheng, SY
    JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 83 (02) : 315 - 322
  • [27] Reactive wetting of polyethylene on ethylene-propylene-diene terpolymer
    Laing, Brittany
    Seveno, David
    De Keyzer, Jozefien
    Van Bael, Albert
    COLLOID AND INTERFACE SCIENCE COMMUNICATIONS, 2021, 40
  • [28] Sulfonation of vulcanized ethylene-propylene-diene terpolymer membranes
    Barroso-Bujans, F.
    Verdejo, R.
    Lozano, A.
    Fierro, J. L. G.
    Lopez-Manchado, M. A.
    ACTA MATERIALIA, 2008, 56 (17) : 4780 - 4788
  • [29] Polypropylene crystallization in an ethylene-propylene-diene rubber matrix
    Manchado, MAL
    Biagiotti, J
    Torre, L
    Kenny, JM
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2000, 61 (02): : 437 - 450
  • [30] NATURAL-RUBBER, NEOPRENE, ETHYLENE-PROPYLENE-DIENE BLENDS IN WHITE SIDEWALL COMPOUNDS
    WINGROVE, DE
    RUBBER CHEMISTRY AND TECHNOLOGY, 1983, 56 (02): : 485 - 486