Modification of Compounds Based on Ethylene-Propylene-Diene Rubbers Using an Oligomeric Unsaturated Polyketone

被引:2
|
作者
Voronchikhin, V. D. [1 ]
Dubkov, K. A. [2 ]
Sorochenko, O. V. [1 ]
Ivanov, D. P. [2 ]
Semikolenov, S. V. [2 ]
机构
[1] Reshetnev Siberian State Univ Sci & Technol, Krasnoyarsk 660037, Russia
[2] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia
基金
俄罗斯基础研究基金会;
关键词
vulcanization; polyketone; modification; ethylene-propylene-diene rubber; elastomers; NITROUS-OXIDE; KETONIZATION;
D O I
10.1134/S1070427220020068
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The efficiency of using an oligomeric unsaturated polyketone prepared by ketonization of cis-1,4-butadiene rubber with nitrogen(I) oxide (N2O) for the modification of physicomechanical properties of elastomer compounds based on Keltan 512 and SKEPT-50 ethylene-propylene-diene rubbers was demonstrated. The modification leads to a decrease in the viscosity of filled rubber stocks, facilitating their processing on the process equipment, and to more uniform dispersion of the silica filler (BS-1290 white soot); it enhances the elastic and strength characteristics of the vulcanizates by a factor of up to 2-2.5 relative to the unmodified compounds.
引用
收藏
页码:197 / 203
页数:7
相关论文
共 50 条
  • [1] Modification of Compounds Based on Ethylene–Propylene–Diene Rubbers Using an Oligomeric Unsaturated Polyketone
    V. D. Voronchikhin
    K. A. Dubkov
    D. P. Ivanov
    S. V. Semikolenov
    Russian Journal of Applied Chemistry, 2020, 93 : 197 - 203
  • [2] Modification of Adhesive Compositions Based on Polar Rubbers with Oligomeric Unsaturated Polyketone
    Voronchikhin, Vasiliy D.
    Dubkov, Konstantin A.
    Semikolenov, Sergei, V
    JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY, 2023, 16 (02): : 266 - 275
  • [3] The structure and thermomechanical properties of ethylene-propylene-diene rubbers
    Livanova, NM
    Evreinov, YV
    Popov, AA
    Shershnev, VA
    POLYMER SCIENCE SERIES A, 2003, 45 (06) : 530 - 536
  • [4] RHEOLOGICAL BEHAVIOR OF BLENDS OF ETHYLENE-PROPYLENE-DIENE AND BROMOBUTYL RUBBERS
    BHAUMIK, TK
    DE, PP
    BHOWMICK, AK
    GUPTA, BR
    INDIAN JOURNAL OF TECHNOLOGY, 1990, 28 (01): : 33 - 38
  • [5] SMOKE PROPERTIES OF HIGHLY FILLED ETHYLENE-PROPYLENE-DIENE TERPOLYMER RUBBERS
    MOSESMAN, M
    INGHAM, JD
    RUBBER CHEMISTRY AND TECHNOLOGY, 1978, 51 (05): : 970 - 976
  • [6] Modification of ethylene-propylene-diene elastomers to improve the ozone resistance of their covulcanizates with butadiene-nitrile rubbers
    Livanova, N. M.
    Shershnev, V. A.
    Dudnik, M. V.
    Andreasyan, Yu O.
    Popov, A. A.
    POLYMER SCIENCE SERIES A, 2011, 53 (02) : 133 - 142
  • [7] Modification of ethylene-propylene-diene elastomers to improve the ozone resistance of their covulcanizates with butadiene-nitrile rubbers
    N. M. Livanova
    V. A. Shershnev
    M. V. Dudnik
    Yu. O. Andreasyan
    A. A. Popov
    Polymer Science Series A, 2011, 53 : 133 - 142
  • [8] ANISOTROPY IN INJECTION-MOLDED ETHYLENE-PROPYLENE-DIENE RUBBERS .1.
    LAVEBRATT, H
    STENBERG, B
    POLYMER ENGINEERING AND SCIENCE, 1994, 34 (11): : 905 - 912
  • [9] Stabilization Effects of Natural Compounds and Polyhedral Oligomeric Silsesquioxane Nanoparticles on the Accelerated Degradation of Ethylene-Propylene-Diene Monomer
    Zaharescu, Traian
    Blanco, Ignazio
    MOLECULES, 2021, 26 (15):
  • [10] The combination of cis-1,4-polyisoprene with ethylene-propylene-diene rubbers and the properties of their covulcanisates
    Livanova, N.M.
    Popov, A.A.
    Shershnev, V.A.
    Yulovskaya, V.D.
    International Polymer Science and Technology, 2013, 40 (01)