5,15-Bis(3,5-di-tert-butylphenyl)-10,20-bis(phenylethynyl)porphyrin

被引：0

作者：

Kim, Hee Jung ^{[1
]}

Singh, Atul P. ^{[1
]}

Kim, Hee-Joon ^{[1
]}

机构：

[1] Kumoh Natl Inst Technol, Dept Appl Chem, Gumi 730701, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

CONJUGATED PORPHYRIN POLYMER; OPTICAL NONLINEARITY; COMPLEXES; CRYSTAL;

D O I：

10.1107/S1600536809045954

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the centrosymmetric title compound, C64H62N 4, the two phenylethynyl groups lie at diagonal meso positions. The 24-membered porphyrin has in-plane distortion with respect to the mean plane of the macrocycle and two intra-ring bifurcated N - H⋯(N,N) hydrogen bonds occur. The dihedral angles between the phenyl rings in the phenylethynyl group and the 3,5-bis-(tert-butyl)phenyl group with respect to the mean plane of the porphyrin are 17.2 (2) and 59.2 (3)°. The tert-butyl groups are disordered over two sets of sites in a 0.661 (13):0.339 (13) ratio.

引用

页码：O3004 / U2087

页数：13

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