Regiospecific solvent-free transfer hydrogenation of α,β-unsaturated carbonyl compounds catalyzed by a cationic ruthenium(II) compound

被引:30
|
作者
Naskar, Sipra [1 ]
Bhattacharjee, Manish [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India
关键词
D O I
10.1016/j.tetlet.2006.11.063
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[(PPh3)(2)Ru(CH3CN)(3)Cl][BPh4] has been found to catalyze the selective reduction of double bonds in alpha,beta-unsaturated ketones with high conversions when formic acid is the hydrogen donor. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:465 / 467
页数:3
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