Crystal structure of LiOiPr•5iPrOH -: a hydrogen-bonded chain structure

被引:0
|
作者
Mehring, M [1 ]
Berkei, M [1 ]
Schürmann, M [1 ]
机构
[1] Univ Dortmund, Fachbereich Chem, Lehrstuhl Anorgan Chem 2, D-44221 Dortmund, Germany
来源
关键词
metal alkoxides; lithium; hydrogen bonding; crystal structure;
D O I
10.1002/1521-3749(200209)628:9/10<1975::AID-ZAAC1975>3.0.CO;2-I
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The title compound was obtained as thin needles from a complex reaction mixture at low temperature. According to the single crystal X-ray structure analysis it crystallizes in the triclinic space group P (1) over bar and consists of solvent separated cations and anions. As a result of hydrogen-bonding a one-dimensional polymer is formed with short O...O distances in the range 2.458(4)-2.709(3)Angstrom.
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页码:1975 / 1978
页数:4
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