Synthesis and crystal structures of thiolate-bridged diruthenium complexes containing two olefinic ligands

被引：7
|
作者：
Qu, JP [1 ]
Matsuzaka, H [1 ]
Ishii, Y [1 ]
Hidai, M [1 ]
机构：
[1] UNIV TOKYO, GRAD SCH ENGN, DEPT CHEM & BIOTECHNOL, BUNKYO KU, TOKYO 113, JAPAN
来源：
CHEMISTRY LETTERS | 1996年 / 09期
关键词：
D O I：
10.1246/cl.1996.767
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of thiolate-bridged dinuclear ruthenium complexes containing two electron-deficient olefinic ligands [Cp*Ru(mu-SR)(2)(eta(2)-C(2)H(3)R')(2)RuCp*] (R = Pr-i, Et, 2,6-C(6)H(3)Me(2) or 2,4,6-C(6)H(2)Me(3); R' = CN, COOMe or CHO) have been synthesized from Ru(II)-Ru(II), Ru(II)-Ru(III) and/or Ru(III)-Ru(III) precursors, three of which have been characterized by X-ray structural analysis.
引用
收藏
页码：767 / 768
页数：2
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