The influence of various reaction parameters on the performance of (α-diimine)nickel(II) catalysts in ethylene oligomerization reactions

被引：6
|
作者：
Helldörfer, M [1 ]
Alt, HG [1 ]
机构：
[1] Univ Bayreuth, Anorgan Chem Lab, D-95440 Bayreuth, Germany
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2003年 / 89卷 / 05期
关键词：
(alpha-diimine)nickel(II) catalysts; oligomerization; alpha-olefins; oligomerization conditions; Lewis bases; additives;
D O I：
10.1002/app.12308
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Modified (alpha-diimine)nickel(II) catalysts are suitable for ethylene oligomerization reactions. Due to the mechanism ("chain running"), the formation of double-bond isomers and branched olefins can be observed. The obtained oligomer mixtures show a Schulz-Flory distribution. Increasing ethylene pressure favors the selectivity of a-olefin formation. The same effect can be observed when Lewis bases like thiophene or furane are added to the oligomer-ization reaction mixture. These results can be related to an interaction of the additives with the catalytic active species during the oligomerization process. (C) 2003 Wiley Periodicals, Inc.
引用
收藏
页码：1356 / 1361
页数：6
相关论文
共 50 条
  • [41] The application of novel dendritic nickel catalysts in the oligomerization of ethylene
    Malgas, R.
    Mapolie, S. F.
    Ojwach, S. O.
    Smith, G. S.
    Darkwa, J.
    CATALYSIS COMMUNICATIONS, 2008, 9 (07) : 1612 - 1617
  • [42] Activated carbon fibers as a support for nickel diimine complexes and their application in ethylene oligomerization
    Variani, Yuri M.
    Lopes, Christian W.
    Nicola, Bruna P.
    Meira, Debora M.
    Pergher, Sibele B. C.
    Bernardo-Gusmao, Katia
    NEW JOURNAL OF CHEMISTRY, 2020, 44 (35) : 15100 - 15108
  • [43] Study of triisobutylaluminum as cocatalyst and processing parameters on ethylene polymerization performance of α-diimine nickel(II) complex by response surface method
    Arabi, H.
    Beheshti, M. S.
    Yousefi, M.
    Hamedani, N. Ghasemi
    Ghafelebashi, M.
    POLYMER BULLETIN, 2013, 70 (10) : 2765 - 2781
  • [44] Study of triisobutylaluminum as cocatalyst and processing parameters on ethylene polymerization performance of α-diimine nickel(II) complex by response surface method
    H. Arabi
    M. S. Beheshti
    M. Yousefi
    N. Ghasemi Hamedani
    M. Ghafelebashi
    Polymer Bulletin, 2013, 70 : 2765 - 2781
  • [45] Highly active supported nickel diimine catalysts for polymerization of ethylene
    Preishuber-Pflugl, P
    Brookhart, M
    MACROMOLECULES, 2002, 35 (16) : 6074 - 6076
  • [46] Synthesis of Supported Nickel Diimine Catalysts for Ethylene Slurry Polymerization
    Choi, Yiyoung
    Soares, Joao B. P.
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2009, 210 (22) : 1979 - 1988
  • [47] Macrocyclic Binuclear a-Diimine Nickel Catalysts for Ethylene Polymerization
    Yang, Jingshuang
    Zhang, Yuxing
    Jian, Zhongbao
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2023, 39 (05) : 797 - 802
  • [48] Synthesis of branched polyethylene using (α-diimine)nickel(II) catalysts:: Influence of temperature, ethylene pressure, and ligand structure on polymer properties
    Gates, DP
    Svejda, SK
    Oñate, E
    Killian, CM
    Johnson, LK
    White, PS
    Brookhart, M
    MACROMOLECULES, 2000, 33 (07) : 2320 - 2334
  • [49] Influence of thiopheneyl-based twisted backbone on the properties of α-diimine nickel catalysts in ethylene polymerization
    Liao, Daohong
    Behzadi, Shabnam
    Hong, Changwen
    Zou, Chen
    Qasim, Muhammad
    Chen, Min
    APPLIED ORGANOMETALLIC CHEMISTRY, 2021, 35 (11)
  • [50] Practical and Theoretical Study on the α-Substituent Effect on α-Diimine Nickel(II) and Cobalt(II)-Based Catalysts for Polymerization of Ethylene
    Khoshsefat, Mostafa
    Beheshti, Narges
    Zohuri, Gholam Hossein
    Ahmadjo, Saeid
    Soleimanzadegan, Somaye
    POLYMER SCIENCE SERIES B, 2016, 58 (05) : 487 - 494
12345