Iron-catalyzed direct amination of azoles using formamides or amines as nitrogen sources in air

被引:133
|
作者
Wang, Jian [1 ]
Hou, Ji-Ting [1 ]
Wen, Jun [1 ]
Zhang, Ji [1 ]
Yu, Xiao-Qi [1 ]
机构
[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China
基金
美国国家科学基金会;
关键词
C-H BONDS; HYDROAMINATION; ALKENES; FUNCTIONALIZATION; ROUTE;
D O I
10.1039/c0cc05811d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new iron-catalyzed, direct C-H amination of azoles at C2 has been developed by using formamides or amines as nitrogen sources. Imidazole is the only additive in the catalyst system and oxygen in air is employed during the transformation process.
引用
收藏
页码:3652 / 3654
页数:3
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