Preparation and Recognition Properties of Molecularly Imprinted Nanofiber Membrane of Chrysin

被引:8
|
作者
Wang, Yaohui [1 ,2 ,3 ,4 ]
Li, Long [1 ,2 ,3 ,4 ]
Cheng, Gege [1 ,2 ,3 ,4 ]
Li, Lanfu [1 ]
Liu, Xiuyu [1 ,2 ,3 ,4 ]
Huang, Qin [1 ,2 ,3 ,4 ]
机构
[1] Guangxi Minzu Univ, Sch Chem & Chem Engn, Nanning 530006, Peoples R China
[2] State Ethn Affairs Commiss, Key Lab Chem & Engn Forest Prod, Nanning 530006, Peoples R China
[3] Guangxi Key Lab Chem & Engn Forest Prod, Nanning 530006, Peoples R China
[4] Guangxi Forest Prod Chem & Engn Collaborat Innova, Nanning 530006, Peoples R China
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
chrysin; electrospinning; molecular imprinting membrane; adsorption; OROXYLUM-INDICUM; SEPARATION; NANOSPHERES; ACID; FABRICATION; ADSORPTION; EXTRACTION; FLAVONOIDS; INVASION;
D O I
10.3390/polym14122398
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The separation and extraction of chrysin from active ingredients of natural products are of great significance, but the existing separation and extraction methods have certain drawbacks. Here, chrysin molecularly imprinted nanofiber membranes (MINMs) were prepared by means of electrospinning using chrysin as a template and polyvinyl alcohol and natural renewable resource rosin ester as membrane materials, which were used for the separation of active components in the natural product. The MINM was examined using Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The adsorption performance, adsorption kinetics, adsorption selectivity, and reusability of the MINM were investigated in static adsorption experiments. The analysis results show that the MINM was successfully prepared with good morphology and thermal stability. The MINM has a good adsorption capacity for chrysin, showing fast adsorption kinetics, and the maximum adsorption capacity was 127.5 mg center dot g(-1), conforming to the Langmuir isotherm model and pseudo-second-order kinetic model. In addition, the MINM exhibited good selectivity and excellent reusability. Therefore, the MINM proposed in this paper is a promising material for the adsorption and separation of chrysin.
引用
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页数:15
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