Rapid and efficient deoxygenation of sulfoxides to sulfides with tantalum(V) chloride/sodium iodide system

被引：7

作者：

Yoo, Byung Woo ^{[1
]}

Park, Jeeyeon ^{[1
]}

Shin, Hyo Jong ^{[1
]}

Yoon, Cheol Min ^{[1
]}

机构：

[1] Korea Univ, Dept Adv Mat Chem, 2511 Sejong Ro, Sejong 339700, South Korea

来源：

JOURNAL OF SULFUR CHEMISTRY | 2017年 / 38卷 / 06期

关键词：

Deoxygenation; sulfoxide; sulfide; tantalum(V) chloride; sodium iodide; REDUCTION; SELENOXIDES; SULFONES; FACILE; MILD;

D O I：

10.1080/17415993.2017.1337770

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

TaCl5/NaI system converts a wide range of sulfoxides to the corresponding sulfides in high yields with short reaction times, under mild conditions. It is worth mentioning that this protocol is chemoselective and tolerates various functional groups (such as -Br, -Cl, -OCH3, -CHO, and -NO2) and double bond. [GRAPHICS] .

引用

页码：597 / 603

页数：7

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