Kinetics of base hydrolysis of low-spin iron(II)-diimine complexes in methanol-water mixtures

被引：0
|
作者：
Abu Gharib, EEA
Gosal, N
Burgess, J [1 ]
机构：
[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England
[2] S Valley Univ, Fac Sci, Sohag 82524, Egypt
来源：
CROATICA CHEMICA ACTA | 2001年 / 74卷 / 03期
关键词：
low-spin iron(II)-diimine complexes; base hydrolysis; kinetics;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Rate constants are reported for base hydrolysis of several low-spin iron(II)-diimine complexes, mostly of polydentate ligands, in water and in aqueous methanol (up to 40% methanol). Rate constant trends from these and earlier studies of a variety of iron(II)-diimine complexes are compared and discussed in terms of ligand structure, ligand substituents, and solvation properties of the various complexes.
引用
收藏
页码：545 / 558
页数：14
相关论文
共 50 条
  • [31] SOLVATION AND REACTIVITY OF IRON(II) DIIMINE COMPLEXES IN DIMETHYL-SULFOXIDE WATER MIXTURES
    ALALOUSY, A
    ALSHEHRI, S
    BLANDAMER, MJ
    BLUNDELL, NJ
    BURGESS, J
    COWLES, HJ
    RADULOVIC, S
    GUARDADO, P
    HUBBARD, CD
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (07): : 1041 - 1047
  • [32] Achieving electroneutrality in low-spin iron(II) complexes that respond to chemical reactants
    Wang, J.
    Hasserodt, J.
    JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2014, 19 : S454 - S454
  • [33] VOLUMES OF ACTIVATION FOR REACTION OF HYDROXIDE WITH SOME LOW-SPIN IRON(II) COMPLEXES
    BURGESS, J
    HUBBARD, CD
    SHERRY, R
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1981, 182 (AUG): : 265 - INOR
  • [34] Scrutinizing Low-Spin Cr(II) Complexes
    Scarborough, Christopher C.
    Sproules, Stephen
    Doonan, Christian J.
    Hagen, Karl S.
    Weyhermueller, Thomas
    Wieghardt, Karl
    INORGANIC CHEMISTRY, 2012, 51 (12) : 6969 - 6982
  • [35] Rate constant for water loss from low-spin iron(II) in aquapentacyanoferrate(II)
    Muriel, F
    Sánchez, F
    Burgess, J
    TRANSITION METAL CHEMISTRY, 2000, 25 (05) : 537 - 540
  • [36] Rate constant for water loss from low-spin iron(II) in aquapentacyanoferrate(II)
    Fernando Muriel
    Francisco Sánchez
    John Burgess
    Transition Metal Chemistry, 2000, 25 : 537 - 540
  • [37] THE ALKALINE AND ACID-HYDROLYSIS OF NORMAL-BUTYLACETATE IN METHANOL-WATER MIXTURES
    SIDAHMED, IM
    SALEM, SM
    HALIM, FMA
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1982, 59 (10) : 1139 - 1144
  • [38] Iron(II) High-Spin and Low-Spin Complexes from Pentaisopropylcyclopentadienyliron(II) Bis(trimethylsilyl)amide
    Gross, Oliver A.
    Lauk, Sergej
    Mueller, Carsten
    Gidt, Wjatscheslaw
    Sun, Yu
    Demeshko, Serhiy
    Meyer, Franc
    Sitzmann, Helmut
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (30) : 3635 - 3643
  • [39] KINETICS AND MECHANISM OF OXIDATION OF ARSENIC(III) BY FERRICYANIDE IN METHANOL-WATER MIXTURES
    ABDELKHALEK, AA
    TRANSITION METAL CHEMISTRY, 1991, 16 (05) : 505 - 507
  • [40] TRANSFER CHEMICAL-POTENTIALS FOR IRON(II)-DIIMINE COMPLEXES FROM WATER INTO AQUEOUS METHANOL
    ABUGHARIB, EEA
    BLANDAMER, MJ
    BURGESS, J
    GOSAL, N
    GUARDADO, P
    SANCHEZ, F
    HUBBARD, CD
    TRANSITION METAL CHEMISTRY, 1984, 9 (08) : 306 - 308
12345