Syntheses, structures and luminescent properties of metal complexes with imidazole-containing polyamine ligand

被引：3

作者：

Lua, Yi ^{[1
]}

Lu, Xi-Hong ^{[1
]}

Huang, Yong-Qing ^{[1
]}

Okamura, Taka-aki ^{[2
]}

Kong, Ling-Yan ^{[1
]}

Sun, Wei-Yin ^{[1
]}

Ueyama, Norikazu ^{[2
]}

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China

[2] Osaka Univ, Dept Macromol Sci, Grad Sch Sci, Osaka, Japan

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2008年 / 634卷 / 04期

关键词：

cadmium; copper; tripodal polyamine ligands; chain structure; fluorescence;

D O I：

10.1002/zaac.200700496

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four novel metal complexes [Cd(L)Cl](BF4) center dot H2O (1), [Cd(L)Br](2)[CdBr4]center dot 2H(2)O (2), [Cu(L)Br]Br (3), and [Cu(L)](NO3)(2) (4) were prepared by the reactions of ligand N-1-(2-aminoethyl)-N-1-(2-imidazolethyl)-ethane-1,2-diamine (L) with metal salts under different reaction conditions. All of these complexes exhibit ID chains, but different structures. The results showed that the pH value of the reaction solution and counter ions have remarkable impact on the structure of the complexes. Furthermore, complexes 1 and 2 represent fluorescence properties in the solid state at room temperature.

引用

页码：708 / 713

页数：6

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