Hydrothermal synthesis, structure and fluorescent property of a coordination compound of urany(VI)

被引：0
|
作者：
Jin Yang-Bo [1 ]
Hu Bin [1 ]
Li Yong-Xiu [1 ]
Wang Guo-Xi [2 ]
机构：
[1] Nanchang Univ, Inst Adv Study, Res Ctr Rare Earth & Micro Nano Funct Mat, Nanchang 330047, Peoples R China
[2] Anyang Inst Technol, Dept Chem & Environm Engn, Anyang 455000, Henan, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 24卷 / 01期
关键词：
uranyl(VI) complex; hydrothermal synthesis; crystal structure; fluorescence;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
UO2(EPC)(2) (EPC=5-ethyl-3-pyridinecarboxylate) was synthesized by the hydrothermal reaction Of UO2(NO3)(2) center dot 6H(2)O with imazethapyr [2-(4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl)-5-ethyl-3-pyridinecarboxylic acid] at 120 degrees C, which 2-(4,5-dlhydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl group was removed under this condition to result in the formation of 5-ethyl-3-pyridinecarboxylate ligand (EPC). The structure and fluorescent property of the synthesized complex is also reported. CCDC: 645641.
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页码：138 / 140
页数：3
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