2D chiral uranyl(VI) coordination polymers with second-harmonic generation response and ferroelectric properties

被引：91
|
作者：
Xie, YR
Zhao, H
Wang, XS
Qu, ZR
Xiong, RG [1 ]
Xue, XA
Xue, ZL
You, XZ
机构：
[1] Beijing Univ, Dept Chem, State Key Lab Rare Earth Mat Chem & Appl, Beijing 100871, Peoples R China
[2] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 20期
关键词：
chirality; polymers; uranium; crystal engineering; SHG properties;
D O I：
10.1002/ejic.200300483
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The in situ hydrothermal reactions Of UO2(NO3)2 with 1-oxo-4-cyanopyridine (ocpy) and ethyl (S)-lactate (e-la) afforded two unprecedented chiral 2D neutral luminescent square grids, uranyl-bis(1-oxo-4-pyridylcarboxylate) UO2(opyca)2 (1) and homochiral uranyl-bis [(S) -lactate] (2). Their solid-state structures, preliminary optical and photoluminescent properties are reported. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).
引用
收藏
页码：3712 / 3715
页数：4
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