An Efficient Synthesis of Vinyl Sulfones from Alkenes and Aryl Sulfinates

被引：40

作者：

Das, Biswanath ^{[1
]}

Lingaiah, Maram ^{[1
]}

Damodar, Kongara ^{[1
]}

Bhunia, Nisith ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Chem Div 1, Hyderabad 500007, Andhra Pradesh, India

来源：

SYNTHESIS-STUTTGART | 2011年 / 18期

关键词：

vinylsulfone; alkene; aryl sulfinate; synthetic methods; ADDITION REACTIONS; HYDROGENOLYSIS; CHEMISTRY; OLEFINS; ACCESS;

D O I：

10.1055/s-0030-1260142

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Vinyl sulfones have been efficiently synthesized by treatment of alkenes with sodium arene sulfinates using potassium iodide and sodium periodate in the presence of a catalytic amount of acetic acid at room temperature. The products are formed in high yields (87-95%) within 2.5-8 hours.

引用

页码：2941 / 2944

页数：4

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