Bis(μ-methanolato-κ2O:O)bis{[4-bromo-N′-(1-methyl-3-oxidobut-2-en-1-ylidene-κO)benzohydrazidato-κ2N′,O]oxidovanadium(V)}

被引：2

作者：

Wong, Hon Wee ^{[1
]}

Lo, Kong Mun ^{[1
]}

Ng, Seik Weng ^{[1
]}

机构：

[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

D O I：

10.1107/S1600536811021647

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The dinuclear compound, [V-2(C12H11BrN2O2)(2)(CH3O)(2)O-2], lies on a center of inversion. The doubly-deprotonated Schiff base O,N,O'-chelates to the V-V atom; two metal atoms are bridged by the methoxide units. The coordination geometry is a distorted octahedron. Weak intermolecular C-H center dot center dot center dot N hydrogen bonding is present in the crystal structure. The bromophenyl unit is disordered over two positions, with the major component being in a 0.909 (6) proportion.

引用

页码：M902 / U797

页数：10

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