Bis(2,2′-bipyridyl)-1κ2N,N′;3κ2N,N′-bis(4-bromo-2-formylphenolato)-1κ2O,O′;3κ2O,O′-bis[μ-2-(5-bromo-2-oxidobenzylideneamino)ethanesulfonato]-1:2κ3O:N,O2;2:3κ3N,O2:O-tricopper(II) monohydrate

被引：0
|
作者：
Zhang, Ling [1 ]
机构：
[1] Lishui Univ, Dept Chem, Lishui 323000, Zhejiang, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
COMPLEXES;
D O I：
10.1107/S1600536809014263
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, [Cu-3(C9H8BrNO4S)(2)(C7H4BrO2)(2)(C10H8N2)(2)]center dot H2O, lies on an inversion center located on the central Cu atom, which is four-coordinated in a square-planar geometry, whereas the outer Cu atoms related by symmetry are five-coordinated in a square-pyramidal geometry. The trinuclear molecules, with an intramolecular Cu center dot center dot center dot Cu separation of 6.313 (3) angstrom, are linked to each other, forming a chain through O-H center dot center dot center dot O and O-H center dot center dot center dot Br hydrogen bonds involving the half-occupied water molecule. Futhermore, weak C-H center dot center dot center dot O interactions link the chains to form a supramolecular network.
引用
收藏
页码：M552 / U812
页数：12
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