Compounds of Mn(II), Co(II) and Ni(II) with Ligand Derived from Morfolin-4 Carboditioic Acid-2(3,5 Diiod, 4 Methyl 2 Hydroxiphenyl) 2-Oxoethylesther

被引：0

作者：

Turcuman , Simona ^{[1
]}

Sibiescu, Doina ^{[1
]}

Rosca, Ioan ^{[1
]}

Cretescu, Igor ^{[2
]}

Rosca, Catalina Yarodara ^{[1
]}

Secula, Marius Sebastian ^{[1
]}

机构：

[1] Gh Asachi Tech Univ, Fac Chem Engn & Environm Protect, Dept Chem Engn, Iasi 700050, Romania

[2] Gh Asachi Tech Univ, Fac Chem Engn & Environm Protect, Environm Engn & Management Dept, Iasi 700050, Romania

来源：

REVISTA DE CHIMIE | 2010年 / 61卷 / 04期

关键词：

Manganese(II); Cobalt(II); Nickel(II); precipitating reagent; gravimetric determination; FE(III); DECOMPOSITION; COMPLEXES;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In order to obtain new compounds of transitional metals having applications in analytical chemistry, we synthesized and studied compounds of Mn(II), Co(II) and Ni(II) with ligand derived from morfolin-4 carboditioic acid-2(3,5-diiod, 4 methyle 2-hydroxiphenyl) 2-oxoethylesther in the molar ratio of 2:1 (ligand to central atom). The characterization of new compounds was performed by means of chemical analysis, derivatographic thermogravimetry, IR absorption spectroscopy, ESR spectroscopy and X-ray diffraction. The investigated compounds are paramagnetic and crystallize in monoclinic system with central atoms Mn(II) , Co(II) or Ni(II) hexacoordinated in octahedral structures. The study of the obtaining reactions of these new compounds supports their use in gravimetric determination of Mn(II), Co(II) and Ni(II).

引用

页码：355 / 359

页数：5

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